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DOI10.1007/s11356-017-9688-8
Light absorption by water-soluble organic carbon in atmospheric fine particles in the central Tibetan Plateau
Zhang, YanGe1,2; Xu, JianZhong1,3,4; Shi, JinSen5; Xie, CongHui1; Ge, XinLei3; Wang, JunFeng3; Kang, ShiChang1; Zhang, Qi3,6
发表日期2017
ISSN0944-1344
EISSN1614-7499
卷号24期号:26页码:21386-21397
英文摘要

Brown carbon (BrC) has recently received much attention because of its light absorption features. The chemical compositions, optical properties, and sources of fine aerosol at a high-elevation mountain observatory (4730 m a.s.l.) in the central Tibetan Plateau were measured between 31 May and 1 July 2015. A low flow-rate sampler was used to collect 24-h average fine particulate matter (PM2.5) filter samples. Water-soluble ions, organic carbon (OC), elemental carbon, water-soluble organic carbon (WSOC), and light absorption by water-soluble BrC were determined for 26 filter samples. The mean (+/- 1 sigma) OC and WSOC concentrations were 0.76 +/- 0.43 and 0.39 +/- 0.15 mu gC/m(3), respectively, and the mean WSOC/OC mass ratio was 0.59 +/- 0.22. The OC and WSOC concentrations were relatively higher (0.59-1.80 and 0.33-0.83 mu gC/m(3), respectively) during the pre-monsoon period (2-13 June) and were relatively lower (0.27-0.77 and 0.12-0.50 mu gC/m(3), respectively) during the monsoon period (14 June to 1 July), probably because of wet scavenging of aerosols during long-range transport and the presence of cleaner marine air masses during the monsoon period. The absorption spectra of PM2.5 water extracts smoothly increase from visible range to ultraviolet range. The absorption ngstrom exponent, which describes the wavelength dependence of water-soluble BrC, was 2.74-10.61 (mean 6.19 +/- 1.70), and its value was similar in the pre-monsoon period (6.57 +/- 0.56) to that in the monsoon period (5.91 +/- 2.14). The water-soluble BrC mass absorption efficiency, 0.38 +/- 0.16 m(2)/(g C), was much lower than those observed in most urban areas but similar to those in other remote sites. Absorption coefficient at 365 nm, typically used as a proxy for water-soluble BrC, correlated well with the WSOC concentration (R-2 = 0.57), K+ concentration (R-2 = 0.75), and organic aerosol biomass burning markers characterized by an Aerodyne aerosol mass spectrometer (C2H4O2+ + C3H5O2 (+), R-2 = 0.60). It can be inferred that biomass burning was an important source of water-soluble BrC in the study area combined with air mass back trajectory analysis using the NOAA HYSPLIT as well as MODIS data of fire dots and aerosol optical depths. The water-soluble BrC to BC light absorption (at 365 nm) coefficient ratios were 9-27%.


英文关键词Brown carbon;Central Tibetan Plateau;PM2.5;Pre-monsoon;Monsoon;Biomass burning
语种英语
WOS研究方向Environmental Sciences & Ecology
来源期刊ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
来源机构中国科学院西北资源环境生态研究院
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/89648
作者单位1.Chinese Acad Sci, Northwest Inst Ecoenvironm & Resources, State Key Lab Cryospher Sci, Lanzhou 730000, Gansu, Peoples R China;;
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China;;
3.Nanjing Univ Informat Sci & Technol, Sch Environm Sci & Engn, Collaborat Innovat Ctr Atmospher Environm & Equip, Jiangsu Key Lab Atmospher Environm Monitoring & P, Nanjing 210044, Jiangsu, Peoples R China;;
4.Chinese Acad Sci, Inst Earth Environm, State Key Lab Loess & Quaternary Geol, Xian 710075, Shaanxi, Peoples R China;;
5.Lanzhou Univ, Coll Atmospher Sci, Minist Educ, Key Lab Semiarid Climate Change, Lanzhou 730000, Gansu, Peoples R China;;
6.Univ Calif Davis, Dept Environm Toxicol, Davis, CA 95616 USA
推荐引用方式
GB/T 7714
Zhang, YanGe,Xu, JianZhong,Shi, JinSen,et al. Light absorption by water-soluble organic carbon in atmospheric fine particles in the central Tibetan Plateau[J]. 中国科学院西北资源环境生态研究院,2017,24(26):21386-21397.
APA Zhang, YanGe.,Xu, JianZhong.,Shi, JinSen.,Xie, CongHui.,Ge, XinLei.,...&Zhang, Qi.(2017).Light absorption by water-soluble organic carbon in atmospheric fine particles in the central Tibetan Plateau.ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH,24(26),21386-21397.
MLA Zhang, YanGe,et al."Light absorption by water-soluble organic carbon in atmospheric fine particles in the central Tibetan Plateau".ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH 24.26(2017):21386-21397.
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