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DOI | 10.5194/acp-18-4617-2018 |
Chemical characterization of long-range transport biomass burning emissions to the Himalayas: insights from high-resolution aerosol mass spectrometry | |
Zhang, Xinghua1,2,3; Xu, Jianzhong1; Kang, Shichang1; Liu, Yanmei1,3; Zhang, Qi4 | |
发表日期 | 2018 |
ISSN | 1680-7316 |
EISSN | 1680-7324 |
卷号 | 18期号:7页码:4617-4638 |
英文摘要 | An intensive field measurement was conducted at a remote, background, high-altitude site (Qomolangma Station, QOMS, 4276 m a.s.l.) in the northern Himalayas, using an Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) along with other collocated instruments. The field measurement was performed from 12 April to 12 May 2016 to chemically characterize the high time-resolved submicron particulate matter (PM1) and obtain the dynamic processes (emissions, transport, and chemical evolution) of biomass burning (BB), frequently transported from South Asia to the Himalayas during pre-monsoon season. Overall, the average (+/- 1 sigma) PM1 mass concentration was 4.44 (+/- 4.54) mu gm(-3) for the entire study, which is comparable with those observed at other remote sites worldwide. Organic aerosol (OA) was the dominant PM1 species (accounting for 54.3% of total PM1 on average) followed by black carbon (BC) (25.0 %), sulfate (9.3 %), ammonium (5.8 %), nitrate (5.1 %), and chloride (0.4 %). The average size distributions of PM1 species all peaked at an overlapping accumulation mode (similar to 500 nm), suggesting that aerosol particles were internally well-mixed and aged during long-range transport. Positive matrix factorization (PMF) analysis on the high-resolution organic mass spectra identified three distinct OA factors, including a BB-related OA (BBOA, 43.7 %), a nitrogen-containing OA (NOA, 13.9 %) and a more-oxidized oxygenated OA (MO-OOA, 42.4 %). Two polluted episodes with enhanced PM1 mass loadings and elevated BBOA contributions from the west and southwest of QOMS during the study were observed. A typical BB plume was investigated in detail to illustrate the chemical evolution of aerosol characteristics under distinct air mass origins, meteorological conditions, and atmospheric oxidation processes. |
语种 | 英语 |
WOS研究方向 | Meteorology & Atmospheric Sciences |
来源期刊 | ATMOSPHERIC CHEMISTRY AND PHYSICS
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来源机构 | 中国科学院西北资源环境生态研究院 |
文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/89588 |
作者单位 | 1.Chinese Acad Sci, Northwest Inst Ecoenvironm & Resources, State Key Lab Cryospher Sci, Lanzhou 730000, Gansu, Peoples R China;; 2.China Meteorol Adm, Inst Arid Meteorol, Key Lab Arid Climat Change & Reducing Disaster Ga, Key Lab Arid Climat Change & Disaster Reduct CMA, Lanzhou 730020, Gansu, Peoples R China;; 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China;; 4.Univ Calif Davis, Dept Environm Toxicol, Davis, CA 95616 USA |
推荐引用方式 GB/T 7714 | Zhang, Xinghua,Xu, Jianzhong,Kang, Shichang,et al. Chemical characterization of long-range transport biomass burning emissions to the Himalayas: insights from high-resolution aerosol mass spectrometry[J]. 中国科学院西北资源环境生态研究院,2018,18(7):4617-4638. |
APA | Zhang, Xinghua,Xu, Jianzhong,Kang, Shichang,Liu, Yanmei,&Zhang, Qi.(2018).Chemical characterization of long-range transport biomass burning emissions to the Himalayas: insights from high-resolution aerosol mass spectrometry.ATMOSPHERIC CHEMISTRY AND PHYSICS,18(7),4617-4638. |
MLA | Zhang, Xinghua,et al."Chemical characterization of long-range transport biomass burning emissions to the Himalayas: insights from high-resolution aerosol mass spectrometry".ATMOSPHERIC CHEMISTRY AND PHYSICS 18.7(2018):4617-4638. |
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