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DOI10.5194/acp-18-4617-2018
Chemical characterization of long-range transport biomass burning emissions to the Himalayas: insights from high-resolution aerosol mass spectrometry
Zhang, Xinghua1,2,3; Xu, Jianzhong1; Kang, Shichang1; Liu, Yanmei1,3; Zhang, Qi4
发表日期2018
ISSN1680-7316
EISSN1680-7324
卷号18期号:7页码:4617-4638
英文摘要

An intensive field measurement was conducted at a remote, background, high-altitude site (Qomolangma Station, QOMS, 4276 m a.s.l.) in the northern Himalayas, using an Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) along with other collocated instruments. The field measurement was performed from 12 April to 12 May 2016 to chemically characterize the high time-resolved submicron particulate matter (PM1) and obtain the dynamic processes (emissions, transport, and chemical evolution) of biomass burning (BB), frequently transported from South Asia to the Himalayas during pre-monsoon season. Overall, the average (+/- 1 sigma) PM1 mass concentration was 4.44 (+/- 4.54) mu gm(-3) for the entire study, which is comparable with those observed at other remote sites worldwide. Organic aerosol (OA) was the dominant PM1 species (accounting for 54.3% of total PM1 on average) followed by black carbon (BC) (25.0 %), sulfate (9.3 %), ammonium (5.8 %), nitrate (5.1 %), and chloride (0.4 %). The average size distributions of PM1 species all peaked at an overlapping accumulation mode (similar to 500 nm), suggesting that aerosol particles were internally well-mixed and aged during long-range transport. Positive matrix factorization (PMF) analysis on the high-resolution organic mass spectra identified three distinct OA factors, including a BB-related OA (BBOA, 43.7 %), a nitrogen-containing OA (NOA, 13.9 %) and a more-oxidized oxygenated OA (MO-OOA, 42.4 %). Two polluted episodes with enhanced PM1 mass loadings and elevated BBOA contributions from the west and southwest of QOMS during the study were observed. A typical BB plume was investigated in detail to illustrate the chemical evolution of aerosol characteristics under distinct air mass origins, meteorological conditions, and atmospheric oxidation processes.


语种英语
WOS研究方向Meteorology & Atmospheric Sciences
来源期刊ATMOSPHERIC CHEMISTRY AND PHYSICS
来源机构中国科学院西北资源环境生态研究院
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/89588
作者单位1.Chinese Acad Sci, Northwest Inst Ecoenvironm & Resources, State Key Lab Cryospher Sci, Lanzhou 730000, Gansu, Peoples R China;;
2.China Meteorol Adm, Inst Arid Meteorol, Key Lab Arid Climat Change & Reducing Disaster Ga, Key Lab Arid Climat Change & Disaster Reduct CMA, Lanzhou 730020, Gansu, Peoples R China;;
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China;;
4.Univ Calif Davis, Dept Environm Toxicol, Davis, CA 95616 USA
推荐引用方式
GB/T 7714
Zhang, Xinghua,Xu, Jianzhong,Kang, Shichang,et al. Chemical characterization of long-range transport biomass burning emissions to the Himalayas: insights from high-resolution aerosol mass spectrometry[J]. 中国科学院西北资源环境生态研究院,2018,18(7):4617-4638.
APA Zhang, Xinghua,Xu, Jianzhong,Kang, Shichang,Liu, Yanmei,&Zhang, Qi.(2018).Chemical characterization of long-range transport biomass burning emissions to the Himalayas: insights from high-resolution aerosol mass spectrometry.ATMOSPHERIC CHEMISTRY AND PHYSICS,18(7),4617-4638.
MLA Zhang, Xinghua,et al."Chemical characterization of long-range transport biomass burning emissions to the Himalayas: insights from high-resolution aerosol mass spectrometry".ATMOSPHERIC CHEMISTRY AND PHYSICS 18.7(2018):4617-4638.
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