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| L BAND SEAWATER DIELECTRIC CONSTANT MEASUREMENTS IN COLD OCEANS AND COASTAL REGIONS | |
| 项目编号 | NNX16AK40G S01 |
| ROGER LANG | |
| 项目主持机构 | GEORGE WASHINGTON UNIVERSITY |
| 开始日期 | 2016-06-01 |
| 结束日期 | 2017-05-31 |
| 英文摘要 | Carboxylic acids are building blocks of utmost importance in our chemical industry, as these motifs are extensively used in the manufacture of soaps, detergents, pharmaceuticals, rubber, plastics, dyes, textile, perfumes, and animal feed, among many others. Current industrial protocols for their synthesis rely heavily on toxic reagents, lengthy-step pathways or waste-producing procedures such as hydrolysis of nitriles or two-step techniques based on hydroformylation of olefins with highly toxic carbon monoxide with expensive noble catalysts (Rh) followed by oxidation. Unlike hydroformylation methods, OLE-DIOX offers the opportunity of promoting a carboxylation event using unactivated olefins, products produced in bulk from petroleum processing, with abundant carbon dioxide as C1 source. The protocol is user-friendly, with components that are neither air- nor moisture sensitive, utilizes earth-abundant catalysts and operates under mild conditions. OLE-DIOX represents an important contribution for our circular economy by effectively recycling bulk materials into valuable products in one-step operation. These unique features makes OLE-DIOX technically and economically viable for its implementation at large-scale en route to industrially-valuable carboxylic acids, thus avoiding lengthy and waste-producing protocols in the established oil-to-carboxylic acid process chain. |
| 学科分类 | 08 - 地球科学;11 - 工程与技术;1107 - 航空航天工程;03 - 天文学 |
| 资助机构 | US-NASA |
| 国家 | US |
| 语种 | 英语 |
| 文献类型 | 项目 |
| 条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/73833 |
| 推荐引用方式 GB/T 7714 | ROGER LANG.L BAND SEAWATER DIELECTRIC CONSTANT MEASUREMENTS IN COLD OCEANS AND COASTAL REGIONS.2016. |
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