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| Polar Olefin Block Copolymers | |
| 项目编号 | ANR-15-CE07-0015 |
| Monsieur Vincent MONTEIL | |
| 项目主持机构 | Université Claude Bernard Lyon 1 - Laboratoire Chimie, Catalyse, Polymères et Procédés |
| 开始日期 | 2015-12-01 |
| 结束日期 | 2019-6-01 |
| 英文摘要 | The purpose of PolarOBC (Polar Olefin Block Copolymers) project is to answer simultaneously two major challenges in the field of polyolefins, the most industrially produced polymers: the control of the synthesis of block copolymers and the introduction of polar functions. For these reasons PolarOBC project undoubtedly meets the societal challenge “Stimulate the industrial renewal” of the ANR generic call 2015. To achieve the synthesis of such block copolymers, PolarOBC will mainly rely on the controlled radical polymerization of apolar olefins, pioneered recently at C2P2 laboratory in the case of ethylene using Reversible Addition Fragmentation chain Transfer (RAFT) technique. Polar/apolar olefin (di)block copolymers will be produced under low energy demanding and environmentally friendly process conditions (T < 100°C; P < 250 bar). While ethylene will be the preferred apolar olefin, targets in terms of polar olefins will be “less-activated” monomers (LAMs) such as vinyl acetate and “more-activated” monomers (MAMs) such as methylmethacrylate (MMA) or acrylates. An important variant of the block copolymers synthetic process will take place in aqueous dispersed media by adapting polymerization-induced (block copolymers) self-assembly (PISA) technique to the case of ethylene. The material properties of the resulting polar OBCs, in particular surface/interface properties linked to their polar/apolar balance, will be evaluated. Their self-assembly properties in bulk and their use to tailor interfaces within polymer blends will be in particular studied. To manage this 42-months project, collaboration between the C2P2 laboratory (for synthetic aspects) and the IMP laboratory (for material evaluation) in Villeurbanne is proposed. The complementary expertise provided by the two research groups will be essential to the success of this ambitious project, which will lead to fully innovative specialty materials (polar OBCs) in the field of polyolefins. |
| 资助机构 | FR-ANR |
| 项目经费 | 346032 |
| 项目类型 | Chimie Durable, produits, procédés associés (DS0304) 2015 |
| URL | http://www.agence-nationale-recherche.fr/en/anr-funded-project/?solr=run&tx_lwmsuivibilan_pi2%5BCODE%5D=ANR-15-CE07-0015 |
| 国家 | FR |
| 语种 | 英语 |
| 文献类型 | 项目 |
| 条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/69837 |
| 推荐引用方式 GB/T 7714 | Monsieur Vincent MONTEIL.Polar Olefin Block Copolymers.2015. |
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