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DOI10.1021/acs.est.7b05509
Sensitivity of Ambient Atmospheric Formaldehyde and Ozone to Precursor Species and Source Types Across the United States
Luecken, D. J.1; Napelenok, S. L.1; Strum, M.2; Scheffe, R.2; Phillips, S.2
发表日期2018-04-17
ISSN0013-936X
卷号52期号:8页码:4668-4675
英文摘要

Formaldehyde (HCHO) is an important air pollutant from both an atmospheric chemistry and human health standpoint. This study uses an instrumented photochemical Air Quality Model, CMAQ-DDM, to identify the sensitivity of HCHO concentrations across the United States (U.S.) to major source types and hydrocarbon speciation. In July, biogenic sources of hydrocarbons contribute the most (92% of total hydrocarbon sensitivity), split between isoprene and other alkenes. Among anthropogenic sources, mobile sources of hydrocarbons and nitrogen oxides (NOx) dominate. In January, HCHO is more sensitive to anthropogenic hydrocarbons than biogenic sources, especially mobile sources and residential wood combustion (36% of national hydrocarbon sensitivity). While ozone (O-3) is three times more sensitive to NOx than hydrocarbons across most areas of the U.S., HCHO is six times more sensitive to hydrocarbons than NOx, largely due to sensitivity to biogenic precursors and the importance of low-NOx chemistry. In winter, both HCHO and O-3 show negative sensitivity to NOx (increases with the removal of NOx), although O-3 increases are larger. Relative sensitivities do not change substantially across different regions of the country.


语种英语
WOS记录号WOS:000430515400020
来源期刊ENVIRONMENTAL SCIENCE & TECHNOLOGY
来源机构美国环保署
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/62564
作者单位1.US EPA, Off Res & Dev, Natl Exposure Res Lab, Res Triangle Pk, NC 27711 USA;
2.US EPA, Off Air Qual Planning & Stand, Res Triangle Pk, NC 27711 USA
推荐引用方式
GB/T 7714
Luecken, D. J.,Napelenok, S. L.,Strum, M.,et al. Sensitivity of Ambient Atmospheric Formaldehyde and Ozone to Precursor Species and Source Types Across the United States[J]. 美国环保署,2018,52(8):4668-4675.
APA Luecken, D. J.,Napelenok, S. L.,Strum, M.,Scheffe, R.,&Phillips, S..(2018).Sensitivity of Ambient Atmospheric Formaldehyde and Ozone to Precursor Species and Source Types Across the United States.ENVIRONMENTAL SCIENCE & TECHNOLOGY,52(8),4668-4675.
MLA Luecken, D. J.,et al."Sensitivity of Ambient Atmospheric Formaldehyde and Ozone to Precursor Species and Source Types Across the United States".ENVIRONMENTAL SCIENCE & TECHNOLOGY 52.8(2018):4668-4675.
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