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DOI | 10.1029/2018JD029284 |
Airborne Observations of Reactive Inorganic Chlorine and Bromine Species in the Exhaust of Coal-Fired Power Plants | |
Lee, Ben H.1; Lopez-Hilfiker, Felipe D.1,2; Schroder, Jason C.3,4; Campuzano-Jost, Pedro3,4; Jimenez, Jose L.3,4; McDuffie, Erin E.3,4,5; Fibiger, Dorothy L.5; Veres, Patrick R.5; Brown, Steven S.4,5; Campos, Teresa L.6; Weinheimer, Andrew J.6; Flocke, Frank F.6; Norris, Gary7; O'; Mara, Kate7; Green, Jaime R.8,9; Fiddler, Marc N.9; Bililign, Solomon8,9; Shah, Viral1; Jaegle, Lyatt1; Thornton, Joel A.1 | |
发表日期 | 2018-10-16 |
ISSN | 2169-897X |
卷号 | 123期号:19页码:11225-11237 |
英文摘要 | We present airborne observations of gaseous reactive halogen species (HCl, Cl-2, ClNO2, Br-2, BrNO2, and BrCl), sulfur dioxide (SO2), and nonrefractory fine particulate chloride (pCl) and sulfate (pSO(4)) in power plant exhaust. Measurements were conducted during the Wintertime INvestigation of Transport, Emissions, and Reactivity campaign in February-March of 2015 aboard the NCAR-NSF C-130 aircraft. Fifty air mass encounters were identified in which SO2 levels were elevated similar to 5 ppb above ambient background levels and in proximity to operational power plants. Each encounter was attributed to one or more potential emission sources using a simple wind trajectory analysis. In case studies, we compare measured emission ratios to those reported in the 2011 National Emissions Inventory and present evidence of the conversion of HCl emitted from power plants to ClNO2. Taking into account possible chemical conversion downwind, there was general agreement between the observed and reported HCl: SO2 emission ratios. Reactive bromine species (Br-2, BrNO2, and/or BrCl) were detected in the exhaust of some coal-fired power plants, likely related to the absence of wet flue gas desulfurization emission control technology. Levels of bromine species enhanced in some encounters exceeded those expected assuming all of the native bromide in coal was released to the atmosphere, though there was no reported use of bromide salts (as a way to reduce mercury emissions) during Wintertime INvestigation of Transport, Emissions, and Reactivity observations. These measurements represent the first ever in-flight observations of reactive gaseous chlorine and bromine containing compounds present in coal-fired power plant exhaust. |
语种 | 英语 |
WOS记录号 | WOS:000448374800026 |
来源期刊 | JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES |
来源机构 | 美国环保署 |
文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/61646 |
作者单位 | 1.Univ Washington, Dept Atmospher Sci, Seattle, WA 98195 USA; 2.Paul Scherrer Inst, Villigen, Switzerland; 3.Univ Colorado, Cooperat Inst Res Environm Sci, Boulder, CO 80309 USA; 4.Univ Colorado, Dept Chem, Boulder, CO 80309 USA; 5.NOAA, Earth Syst Res Lab, Chem Sci Div, Boulder, CO USA; 6.Natl Ctr Atmospher Res, POB 3000, Boulder, CO 80307 USA; 7.US EPA, Res Triangle Pk, NC 27711 USA; 8.North Carolina Agr & Tech State Univ, Dept Phys, Greensboro, NC USA; 9.North Carolina Agr & Tech State Univ, NOAA ISET Ctr, Greensboro, NC USA |
推荐引用方式 GB/T 7714 | Lee, Ben H.,Lopez-Hilfiker, Felipe D.,Schroder, Jason C.,et al. Airborne Observations of Reactive Inorganic Chlorine and Bromine Species in the Exhaust of Coal-Fired Power Plants[J]. 美国环保署,2018,123(19):11225-11237. |
APA | Lee, Ben H..,Lopez-Hilfiker, Felipe D..,Schroder, Jason C..,Campuzano-Jost, Pedro.,Jimenez, Jose L..,...&Thornton, Joel A..(2018).Airborne Observations of Reactive Inorganic Chlorine and Bromine Species in the Exhaust of Coal-Fired Power Plants.JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES,123(19),11225-11237. |
MLA | Lee, Ben H.,et al."Airborne Observations of Reactive Inorganic Chlorine and Bromine Species in the Exhaust of Coal-Fired Power Plants".JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES 123.19(2018):11225-11237. |
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