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DOI10.1029/2018JD029284
Airborne Observations of Reactive Inorganic Chlorine and Bromine Species in the Exhaust of Coal-Fired Power Plants
Lee, Ben H.1; Lopez-Hilfiker, Felipe D.1,2; Schroder, Jason C.3,4; Campuzano-Jost, Pedro3,4; Jimenez, Jose L.3,4; McDuffie, Erin E.3,4,5; Fibiger, Dorothy L.5; Veres, Patrick R.5; Brown, Steven S.4,5; Campos, Teresa L.6; Weinheimer, Andrew J.6; Flocke, Frank F.6; Norris, Gary7; O'; Mara, Kate7; Green, Jaime R.8,9; Fiddler, Marc N.9; Bililign, Solomon8,9; Shah, Viral1; Jaegle, Lyatt1; Thornton, Joel A.1
发表日期2018-10-16
ISSN2169-897X
卷号123期号:19页码:11225-11237
英文摘要

We present airborne observations of gaseous reactive halogen species (HCl, Cl-2, ClNO2, Br-2, BrNO2, and BrCl), sulfur dioxide (SO2), and nonrefractory fine particulate chloride (pCl) and sulfate (pSO(4)) in power plant exhaust. Measurements were conducted during the Wintertime INvestigation of Transport, Emissions, and Reactivity campaign in February-March of 2015 aboard the NCAR-NSF C-130 aircraft. Fifty air mass encounters were identified in which SO2 levels were elevated similar to 5 ppb above ambient background levels and in proximity to operational power plants. Each encounter was attributed to one or more potential emission sources using a simple wind trajectory analysis. In case studies, we compare measured emission ratios to those reported in the 2011 National Emissions Inventory and present evidence of the conversion of HCl emitted from power plants to ClNO2. Taking into account possible chemical conversion downwind, there was general agreement between the observed and reported HCl: SO2 emission ratios. Reactive bromine species (Br-2, BrNO2, and/or BrCl) were detected in the exhaust of some coal-fired power plants, likely related to the absence of wet flue gas desulfurization emission control technology. Levels of bromine species enhanced in some encounters exceeded those expected assuming all of the native bromide in coal was released to the atmosphere, though there was no reported use of bromide salts (as a way to reduce mercury emissions) during Wintertime INvestigation of Transport, Emissions, and Reactivity observations. These measurements represent the first ever in-flight observations of reactive gaseous chlorine and bromine containing compounds present in coal-fired power plant exhaust.


语种英语
WOS记录号WOS:000448374800026
来源期刊JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES
来源机构美国环保署
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/61646
作者单位1.Univ Washington, Dept Atmospher Sci, Seattle, WA 98195 USA;
2.Paul Scherrer Inst, Villigen, Switzerland;
3.Univ Colorado, Cooperat Inst Res Environm Sci, Boulder, CO 80309 USA;
4.Univ Colorado, Dept Chem, Boulder, CO 80309 USA;
5.NOAA, Earth Syst Res Lab, Chem Sci Div, Boulder, CO USA;
6.Natl Ctr Atmospher Res, POB 3000, Boulder, CO 80307 USA;
7.US EPA, Res Triangle Pk, NC 27711 USA;
8.North Carolina Agr & Tech State Univ, Dept Phys, Greensboro, NC USA;
9.North Carolina Agr & Tech State Univ, NOAA ISET Ctr, Greensboro, NC USA
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Lee, Ben H.,Lopez-Hilfiker, Felipe D.,Schroder, Jason C.,et al. Airborne Observations of Reactive Inorganic Chlorine and Bromine Species in the Exhaust of Coal-Fired Power Plants[J]. 美国环保署,2018,123(19):11225-11237.
APA Lee, Ben H..,Lopez-Hilfiker, Felipe D..,Schroder, Jason C..,Campuzano-Jost, Pedro.,Jimenez, Jose L..,...&Thornton, Joel A..(2018).Airborne Observations of Reactive Inorganic Chlorine and Bromine Species in the Exhaust of Coal-Fired Power Plants.JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES,123(19),11225-11237.
MLA Lee, Ben H.,et al."Airborne Observations of Reactive Inorganic Chlorine and Bromine Species in the Exhaust of Coal-Fired Power Plants".JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES 123.19(2018):11225-11237.
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