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DOI10.1021/acs.est.7b02904
Updated Polychlorinated Biphenyl Mass Budget for Lake Michigan
Guo, Jiehong1; Romanak, Kevin1; Westenbroek, Stephen2; Li, An3; Kreis, Russell G., Jr.4; Hites, Ronald A.1; Venier, Marta1
发表日期2017-11-07
ISSN0013-936X
卷号51期号:21页码:12455-12465
英文摘要

This study revisits and updates the Lake Michigan Mass Balance Project (LMMBP) for polychlorinated biphenyls (PCBs) that was conducted in 1994-1995. This work uses recent concentrations of PCBs in tributary and open lake water, air, and sediment to calculate an updated mass budget. Five of the 11 LMMBP tributaries were revisited in 2015. In these five tributaries, the geometric mean concentrations of Sigma PCBs (sum of 85 congeners) ranged from 1.52 to 22.4 ng L-1. The highest concentrations of Sigma PCBs were generally found in the Lower Fox River and in the Indiana Harbor and Ship Canal. The input flows of Sigma PCBs from wet deposition, dry deposition, tributary loading, and air to water exchange, and the output flows due to sediment burial, volatilization from water to air, and transport to Lake Huron and through the Chicago Diversion were calculated, as well as flows related to the internal, processes of settling, resuspension, and sediment -Water diffusion. The net transfer of Sigma PCBs is 1240 +/- 531 kg yr(-1) out of the lake. This net transfer is 46% lower than that estimated in 1994-1995. PCB concentrations in most "matrices in the lake are decreasing,,which drove the decline of all the individual input and output flows. Atmospheric deposition has become negligible, while volatilization from the water surface is still a major "route of loss, releasing PCBs from the lake into the air. Large masses of PCBs remain in the water column and surface sediments and are likely to contribute to the future efflux of PCBs from the lake to the air.


语种英语
WOS记录号WOS:000414887200046
来源期刊ENVIRONMENTAL SCIENCE & TECHNOLOGY
来源机构美国环保署
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/61261
作者单位1.Indiana Univ, Sch Publ & Environm Affairs, Bloomington, IN 47405 USA;
2.US Geol Survey, Wisconsin Water Sci Ctr, Middleton, WI 53562 USA;
3.Univ Illinois, Sch Publ Hlth, Chicago, IL 60612 USA;
4.US EPA, Off Res & Dev, Grosse Ile, MI 48138 USA
推荐引用方式
GB/T 7714
Guo, Jiehong,Romanak, Kevin,Westenbroek, Stephen,et al. Updated Polychlorinated Biphenyl Mass Budget for Lake Michigan[J]. 美国环保署,2017,51(21):12455-12465.
APA Guo, Jiehong.,Romanak, Kevin.,Westenbroek, Stephen.,Li, An.,Kreis, Russell G., Jr..,...&Venier, Marta.(2017).Updated Polychlorinated Biphenyl Mass Budget for Lake Michigan.ENVIRONMENTAL SCIENCE & TECHNOLOGY,51(21),12455-12465.
MLA Guo, Jiehong,et al."Updated Polychlorinated Biphenyl Mass Budget for Lake Michigan".ENVIRONMENTAL SCIENCE & TECHNOLOGY 51.21(2017):12455-12465.
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