Climate Change Data Portal
DOI | 10.5194/acp-16-1245-2016 |
Constraining condensed-phase formation kinetics of secondary organic aerosol components from isoprene epoxydiols | |
Riedel, T. P.1,3; Lin, Y. -H.1,4; Zhang, Z.1; Chu, K.1; Thornton, J. A.2; Vizuete, W.1; Gold, A.1; Surratt, J. D.1 | |
发表日期 | 2016 |
ISSN | 1680-7316 |
卷号 | 16期号:3页码:1245-1254 |
英文摘要 | Isomeric epoxydiols from isoprene photooxidation (IEPOX) have been shown to produce substantial amounts of secondary organic aerosol (SOA) mass and are therefore considered a major isoprene-derived SOA precursor. Heterogeneous reactions of IEPOX on atmospheric aerosols form various aerosol-phase components or "tracers" that contribute to the SOA mass burden. A limited number of the reaction rate constants for these acid-catalyzed aqueous-phase tracer formation reactions have been constrained through bulk laboratory measurements. We have designed a chemical box model with multiple experimental constraints to explicitly simulate gas-and aqueous-phase reactions during chamber experiments of SOA growth from IEPOX uptake onto acidic sulfate aerosol. The model is constrained by measurements of the IEPOX reactive uptake coefficient, IEPOX and aerosol chamber wall losses, chamber-measured aerosol mass and surface area concentrations, aerosol thermodynamic model calculations, and offline filter-based measurements of SOA tracers. By requiring the model output to match the SOA growth and offline filter measurements collected during the chamber experiments, we derive estimates of the tracer formation reaction rate constants that have not yet been measured or estimated for bulk solutions. |
语种 | 英语 |
WOS记录号 | WOS:000371284100003 |
来源期刊 | ATMOSPHERIC CHEMISTRY AND PHYSICS
![]() |
来源机构 | 美国环保署 |
文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/61009 |
作者单位 | 1.Univ N Carolina, Dept Environm Sci & Engn, Gillings Sch Global Publ Hlth, Chapel Hill, NC USA; 2.Univ Washington, Dept Atmospher Sci, Seattle, WA 98195 USA; 3.US EPA, Natl Exposure Res Lab, Res Triangle Pk, NC 27711 USA; 4.Univ Michigan, Michigan Soc Fellows, Dept Chem, Ann Arbor, MI 48109 USA |
推荐引用方式 GB/T 7714 | Riedel, T. P.,Lin, Y. -H.,Zhang, Z.,et al. Constraining condensed-phase formation kinetics of secondary organic aerosol components from isoprene epoxydiols[J]. 美国环保署,2016,16(3):1245-1254. |
APA | Riedel, T. P..,Lin, Y. -H..,Zhang, Z..,Chu, K..,Thornton, J. A..,...&Surratt, J. D..(2016).Constraining condensed-phase formation kinetics of secondary organic aerosol components from isoprene epoxydiols.ATMOSPHERIC CHEMISTRY AND PHYSICS,16(3),1245-1254. |
MLA | Riedel, T. P.,et al."Constraining condensed-phase formation kinetics of secondary organic aerosol components from isoprene epoxydiols".ATMOSPHERIC CHEMISTRY AND PHYSICS 16.3(2016):1245-1254. |
条目包含的文件 | 条目无相关文件。 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。