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DOI | 10.1016/j.colsurfa.2014.05.041 |
Transport of fluorescently labeled hydroxyapatite nanoparticles in saturated granular media at environmentally relevant concentrations of surfactants | |
Wang, Dengjun1,4; Su, Chunming2; Liu, Chongxuan3; Zhou, Dongmei1 | |
发表日期 | 2014-09-05 |
ISSN | 0927-7757 |
卷号 | 457页码:58-66 |
英文摘要 | Little is known about the mobility of engineered nanoparticles (ENPs) in granular media at environmentally relevant concentrations of surfactants, which represents a critical knowledge gap in employing ENPs for in situ remediation of contaminated groundwater. In this study, transport and retention of alizarin red S (ARS)-labeled hydroxyapatite nanoparticle (nHAP) were investigated in water-saturated sand at environmentally relevant concentrations of surfactants: anionic sodium dodecyl benzene sulfonate (SDBS, 0-50 mg L-1) and cationic cetyltrimethylammonium bromide (CTAB, 0-5 mg L-1). Transport of ARS-nHAP increased with increasing SDBS concentration because of enhanced colloidal stability and reduced aggregate size arising from enhanced electrostatic, osmotic, and elastic-steric repulsions between ARS-nHAP and sand grains. In contrast, transport decreased significantly with increasing CTAB concentration due to reduced surface charge and enhanced aggregation of ARS-nHAP. Osmotic and elastic-steric repulsions played a minor role in enhancing ARS-nHAP colloidal stability in CTAB tests. Retention profiles of ARS-nHAP exhibited hyperexponential-shapes for all conditions tested and became more pronounced as CTAB concentration increased. The phenomenon was attributed to the aggregation and ripening of ARS-nHAP in the presence of surfactants, particularly CTAB. Overall, the present study suggests that surfactant type and concentration may be important considerations in employing nHAP for engineered in situ remediation of metal- and radionuclide-contaminated groundwater. (C) 2014 Elsevier B.V. All rights reserved. |
英文关键词 | Hydroxyapatite nanoparticle;Surfactant;Transport;Ripening;Porous media;Groundwater remediation |
语种 | 英语 |
WOS记录号 | WOS:000340340600008 |
来源期刊 | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS |
来源机构 | 美国环保署 |
文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/60770 |
作者单位 | 1.Chinese Acad Sci, Inst Soil Sci, Key Lab Soil Environm & Pollut Remediat, Nanjing 210008, Jiangsu, Peoples R China; 2.US EPA, Ground Water & Ecosyst Restorat Div, Natl Risk Management Res Lab, Off Res & Dev, Ada, OK 74820 USA; 3.Pacific NW Natl Lab, Div Chem & Mat Sci, Fundamental & Computat Sci Directorate, Richland, WA 99354 USA; 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Dengjun,Su, Chunming,Liu, Chongxuan,et al. Transport of fluorescently labeled hydroxyapatite nanoparticles in saturated granular media at environmentally relevant concentrations of surfactants[J]. 美国环保署,2014,457:58-66. |
APA | Wang, Dengjun,Su, Chunming,Liu, Chongxuan,&Zhou, Dongmei.(2014).Transport of fluorescently labeled hydroxyapatite nanoparticles in saturated granular media at environmentally relevant concentrations of surfactants.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,457,58-66. |
MLA | Wang, Dengjun,et al."Transport of fluorescently labeled hydroxyapatite nanoparticles in saturated granular media at environmentally relevant concentrations of surfactants".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 457(2014):58-66. |
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