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DOI10.1016/j.colsurfa.2014.05.041
Transport of fluorescently labeled hydroxyapatite nanoparticles in saturated granular media at environmentally relevant concentrations of surfactants
Wang, Dengjun1,4; Su, Chunming2; Liu, Chongxuan3; Zhou, Dongmei1
发表日期2014-09-05
ISSN0927-7757
卷号457页码:58-66
英文摘要

Little is known about the mobility of engineered nanoparticles (ENPs) in granular media at environmentally relevant concentrations of surfactants, which represents a critical knowledge gap in employing ENPs for in situ remediation of contaminated groundwater. In this study, transport and retention of alizarin red S (ARS)-labeled hydroxyapatite nanoparticle (nHAP) were investigated in water-saturated sand at environmentally relevant concentrations of surfactants: anionic sodium dodecyl benzene sulfonate (SDBS, 0-50 mg L-1) and cationic cetyltrimethylammonium bromide (CTAB, 0-5 mg L-1). Transport of ARS-nHAP increased with increasing SDBS concentration because of enhanced colloidal stability and reduced aggregate size arising from enhanced electrostatic, osmotic, and elastic-steric repulsions between ARS-nHAP and sand grains. In contrast, transport decreased significantly with increasing CTAB concentration due to reduced surface charge and enhanced aggregation of ARS-nHAP. Osmotic and elastic-steric repulsions played a minor role in enhancing ARS-nHAP colloidal stability in CTAB tests. Retention profiles of ARS-nHAP exhibited hyperexponential-shapes for all conditions tested and became more pronounced as CTAB concentration increased. The phenomenon was attributed to the aggregation and ripening of ARS-nHAP in the presence of surfactants, particularly CTAB. Overall, the present study suggests that surfactant type and concentration may be important considerations in employing nHAP for engineered in situ remediation of metal- and radionuclide-contaminated groundwater. (C) 2014 Elsevier B.V. All rights reserved.


英文关键词Hydroxyapatite nanoparticle;Surfactant;Transport;Ripening;Porous media;Groundwater remediation
语种英语
WOS记录号WOS:000340340600008
来源期刊COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
来源机构美国环保署
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/60770
作者单位1.Chinese Acad Sci, Inst Soil Sci, Key Lab Soil Environm & Pollut Remediat, Nanjing 210008, Jiangsu, Peoples R China;
2.US EPA, Ground Water & Ecosyst Restorat Div, Natl Risk Management Res Lab, Off Res & Dev, Ada, OK 74820 USA;
3.Pacific NW Natl Lab, Div Chem & Mat Sci, Fundamental & Computat Sci Directorate, Richland, WA 99354 USA;
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Wang, Dengjun,Su, Chunming,Liu, Chongxuan,et al. Transport of fluorescently labeled hydroxyapatite nanoparticles in saturated granular media at environmentally relevant concentrations of surfactants[J]. 美国环保署,2014,457:58-66.
APA Wang, Dengjun,Su, Chunming,Liu, Chongxuan,&Zhou, Dongmei.(2014).Transport of fluorescently labeled hydroxyapatite nanoparticles in saturated granular media at environmentally relevant concentrations of surfactants.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,457,58-66.
MLA Wang, Dengjun,et al."Transport of fluorescently labeled hydroxyapatite nanoparticles in saturated granular media at environmentally relevant concentrations of surfactants".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 457(2014):58-66.
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