Climate Change Data Portal
DOI | 10.5194/acp-16-7135-2016 |
Characterization of polar organosulfates in secondary organic aerosol from the unsaturated aldehydes 2-E-pentenal, 2-E-hexenal, and 3-Z-hexenal | |
Shalamzari, Mohammad Safi1,2; Vermeylen, Reinhilde1; Blockhuys, Frank3; Kleindienst, Tadeusz E.4; Lewandowski, Michael4; Szmigielski, Rafal5; Rudzinski, Krzysztof J.5; Spolnik, Grzegorz6; Danikiewicz, Witold6; Maenhaut, Willy1,2; Claeys, Magda1 | |
发表日期 | 2016 |
ISSN | 1680-7316 |
卷号 | 16期号:11页码:7135-7148 |
英文摘要 | We show in the present study that the unsaturated aldehydes 2-E-pentenal, 2-E-hexenal, and 3-Z-hexenal are biogenic volatile organic compound (BVOC) precursors for polar organosulfates with molecular weights (MWs) 230 and 214, which are also present in ambient fine aerosol from a forested site, i.e., K-puszta, Hungary. These results complement those obtained in a previous study showing that the green leaf aldehyde 3-Z-hexenal serves as a precursor for MW 226 organosulfates. Thus, in addition to isoprene, the green leaf volatiles (GLVs) 2-E-hexenal and 3-Z-hexenal, emitted due to plant stress (mechanical wounding or insect attack), and 2-E-pentenal, a photolysis product of 3-Z-hexenal, should be taken into account for secondary organic aerosol and organosulfate formation. Polar organosulfates are of climatic relevance because of their hydrophilic properties and cloud effects. Extensive use was made of organic mass spectrometry (MS) and detailed interpretation of MS data (i.e., ion trap MS and accurate mass measurements) to elucidate the chemical structures of the MW 230, 214 and 170 organosulfates formed from 2-E-pentenal and indirectly from 2-E-hexenal and 3-Z-hexenal. In addition, quantum chemical calculations were performed to explain the different mass spectral behavior of 2,3-dihydroxypentanoic acid sulfate derivatives, where only the isomer with the sulfate group at C-3 results in the loss of SO3. The MW 214 organosulfates formed from 2-E-pentenal are explained by epoxidation of the double bond in the gas phase and sulfation of the epoxy group with sulfuric acid in the particle phase through the same pathway as that proposed for 3-sulfooxy-2-hydroxy-2-methylpropanoic acid from the isoprene-related alpha,beta-unsaturated aldehyde methacrolein in previous work (Lin et al., 2013). The MW 230 organosulfates formed from 2-E-pentenal are tentatively explained by a novel pathway, which bears features of the latter pathway but introduces an additional hydroxyl group at the C-4 position. Evidence is also presented that the MW 214 positional isomer, 2-sulfooxy-3-hydroxypentanoic acid, is unstable and decarboxylates, giving rise to 1-sulfooxy-2-hydroxybutane, a MW 170 organosulfate. Furthermore, evidence is obtained that lactic acid sulfate is generated from 2-E-pentenal. This chemistry could be important on a regional and local scale where GLV emissions such as from grasses and cereal crops are substantial. |
语种 | 英语 |
WOS记录号 | WOS:000378354600029 |
来源期刊 | ATMOSPHERIC CHEMISTRY AND PHYSICS |
来源机构 | 美国环保署 |
文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/60548 |
作者单位 | 1.Univ Antwerp, Dept Pharmaceut Sci, B-2610 Antwerp, Belgium; 2.Univ Ghent, Dept Analyt Chem, B-9000 Ghent, Belgium; 3.Univ Antwerp, Dept Chem, B-2020 Antwerp, Belgium; 4.US EPA, Natl Exposure Res Lab, Off Res & Dev, Res Triangle Pk, NC 27711 USA; 5.Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland; 6.Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland |
推荐引用方式 GB/T 7714 | Shalamzari, Mohammad Safi,Vermeylen, Reinhilde,Blockhuys, Frank,et al. Characterization of polar organosulfates in secondary organic aerosol from the unsaturated aldehydes 2-E-pentenal, 2-E-hexenal, and 3-Z-hexenal[J]. 美国环保署,2016,16(11):7135-7148. |
APA | Shalamzari, Mohammad Safi.,Vermeylen, Reinhilde.,Blockhuys, Frank.,Kleindienst, Tadeusz E..,Lewandowski, Michael.,...&Claeys, Magda.(2016).Characterization of polar organosulfates in secondary organic aerosol from the unsaturated aldehydes 2-E-pentenal, 2-E-hexenal, and 3-Z-hexenal.ATMOSPHERIC CHEMISTRY AND PHYSICS,16(11),7135-7148. |
MLA | Shalamzari, Mohammad Safi,et al."Characterization of polar organosulfates in secondary organic aerosol from the unsaturated aldehydes 2-E-pentenal, 2-E-hexenal, and 3-Z-hexenal".ATMOSPHERIC CHEMISTRY AND PHYSICS 16.11(2016):7135-7148. |
条目包含的文件 | 条目无相关文件。 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。