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DOI | 10.1021/acs.est.7b03263 |
Light Absorption of Secondary Organic Aerosol: Composition and Contribution of Nitroaromatic Compounds | |
Xie, Mingjie1,2,3; Chen, Xi3; Hays, Michael D.3; Lewandowski, Michael4; Offenberg, John4; Kleindienst, Tadeusz E.4; Holder, Amara L.3 | |
发表日期 | 2017-10-17 |
ISSN | 0013-936X |
卷号 | 51期号:20页码:11607-11616 |
英文摘要 | Secondary organic aerosol (SOA) can affect the atmospheric radiation balance through absorbing light at shorter visible and UV wavelengths. However, the composition and optical properties of light-absorbing SOA is poorly understood. In this work, SOA filter samples were collected during individual chamber experiments conducted with three biogenic and eight aromatic volatile organic compound (VOC) precursors in the presence of NOx and H2O2. Compared with the SOA generated using the aromatic precursors, biogenic SOA generally exhibits negligible light absorption above 350 nm; the aromatic SOA generated in the presence of NOx shows stronger light absorption than that generated with H2O2. Fifteen nitroaromatic compound (NAC) chemical formulas were identified and quantified in SOA samples. Their contributions to the light absorption of sample extracts were also estimated. On average, the m-cresol/NOx SOA sample has the highest mass contribution from NACs (10.4 +/- 6.74%, w/w), followed by naphthalene/NOx (6.41 +/- 2.08%) and benzene/NOx (5.81 +/- 3.82%) SOA. The average contributions of NACs to total light absorption were at least two times greater than their average mass contributions at 365 and 400 nm, revealing the potential use of chromophoric NACs as brown carbon (BrC) tracers in source apportionment and air quality modeling studies. |
语种 | 英语 |
WOS记录号 | WOS:000413391800015 |
来源期刊 | ENVIRONMENTAL SCIENCE & TECHNOLOGY |
来源机构 | 美国环保署 |
文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/59227 |
作者单位 | 1.Nanjing Univ Informat Sci & Technol, Sch Environm Sci & Engn, Nanjing 210044, Jiangsu, Peoples R China; 2.US EPA, Oak Ridge Inst Sci & Educ, Off Res & Dev, 109 TW Alexander Dr, Res Triangle Pk, NC 27711 USA; 3.US EPA, Natl Risk Management Res Lab, Off Res & Dev, 109 TW Alexander Dr, Res Triangle Pk, NC 27711 USA; 4.US EPA, Natl Exposure Res Lab, Off Res & Dev, 109 TW Alexander Dr, Res Triangle Pk, NC 27711 USA |
推荐引用方式 GB/T 7714 | Xie, Mingjie,Chen, Xi,Hays, Michael D.,et al. Light Absorption of Secondary Organic Aerosol: Composition and Contribution of Nitroaromatic Compounds[J]. 美国环保署,2017,51(20):11607-11616. |
APA | Xie, Mingjie.,Chen, Xi.,Hays, Michael D..,Lewandowski, Michael.,Offenberg, John.,...&Holder, Amara L..(2017).Light Absorption of Secondary Organic Aerosol: Composition and Contribution of Nitroaromatic Compounds.ENVIRONMENTAL SCIENCE & TECHNOLOGY,51(20),11607-11616. |
MLA | Xie, Mingjie,et al."Light Absorption of Secondary Organic Aerosol: Composition and Contribution of Nitroaromatic Compounds".ENVIRONMENTAL SCIENCE & TECHNOLOGY 51.20(2017):11607-11616. |
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