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DOI10.1039/c5ta08386a
Micro-mesoporous iron oxides with record efficiency for the decomposition of hydrogen peroxide: morphology driven catalysis for the degradation of organic contaminants
Datta, K. J.1; Gawande, M. B.1; Datta, K. K. R.1; Ranc, V.1; Pechousek, J.1; Krizek, M.1; Tucek, J.1; Kale, R.2; Pospisil, P.2; Varma, R. S.3; Asefa, T.4; Zoppellaro, G.1; Zboril, R.1
发表日期2016
ISSN2050-7488
卷号4期号:2页码:596-604
英文摘要

A template-free solid-state synthesis of a morphologically controlled and highly organized iron(III) oxide micro-mesoporous Fenton catalyst has been engineered through a simple two-step synthetic procedure. The 3D nanoassembly of hematite nanoparticles (5-7 nm) organized into a rod/flower-like morphology shows the highest rate constant reported to date for the decomposition of H2O2 (1.43 x 10(-1) min(-1)) with superior efficiency for the degradation of aromatic (phenol, benzene, ethylbenzene) and chlorinated (trichloroethylene) pollutants in contaminated water. The morphological arrangement of nanoparticles is therefore considered one of the key variables that drive catalysis.


语种英语
WOS记录号WOS:000367272800031
来源期刊JOURNAL OF MATERIALS CHEMISTRY A
来源机构美国环保署
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/58958
作者单位1.Palacky Univ, Fac Sci, Dept Phys Chem, Reg Ctr Adv Technol & Mat, Olomouc 78371, Czech Republic;
2.Palacky Univ, Fac Sci, Dept Biophys, Ctr Reg Hana Biotechnol & Agr Res, Olomouc 78371, Czech Republic;
3.US EPA, Sustainable Technol Div, Natl Risk Management Res Lab, Cincinnati, OH USA;
4.Rutgers State Univ, Dept Chem & Biochem Engn, Dept Chem & Chem Biol, Piscataway, NJ 08854 USA
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GB/T 7714
Datta, K. J.,Gawande, M. B.,Datta, K. K. R.,et al. Micro-mesoporous iron oxides with record efficiency for the decomposition of hydrogen peroxide: morphology driven catalysis for the degradation of organic contaminants[J]. 美国环保署,2016,4(2):596-604.
APA Datta, K. J..,Gawande, M. B..,Datta, K. K. R..,Ranc, V..,Pechousek, J..,...&Zboril, R..(2016).Micro-mesoporous iron oxides with record efficiency for the decomposition of hydrogen peroxide: morphology driven catalysis for the degradation of organic contaminants.JOURNAL OF MATERIALS CHEMISTRY A,4(2),596-604.
MLA Datta, K. J.,et al."Micro-mesoporous iron oxides with record efficiency for the decomposition of hydrogen peroxide: morphology driven catalysis for the degradation of organic contaminants".JOURNAL OF MATERIALS CHEMISTRY A 4.2(2016):596-604.
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