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DOI | 10.1021/ez5001353 |
Contribution of Isoprene Epoxydiol to Urban Organic Aerosol: Evidence from Modeling and Measurements | |
Karambelas, Alexandra1; Pye, Havala O. T.1; Budisulistiorini, Sri H.2; Surratt, Jason D.2; Pinder, Robert W.1 | |
发表日期 | 2014-06-01 |
ISSN | 2328-8930 |
卷号 | 1期号:6页码:278-283 |
英文摘要 | In a region heavily influenced by anthropogenic and biogenic atmospheric emissions, recent field measurements have attributed one-third of urban organic aerosol by mass to isoprene epoxydiols (IEPOX). These aerosols arise from the gas-phase oxidation of isoprene, the formation of IEPOX, the reactive uptake of IEPOX by particles, and finally the formation of new compounds in the aerosol phase. Using a continental-scale chemical transport model, we find a strong temporal correspondence between the simulated formation of IEPOX-derived organic aerosol and these measurements. However, because only a subset of isoprene-derived aerosol compounds have been specifically identified in laboratory studies, our simulation of known IEPOX-derived organic aerosol compounds predicts a mass 10-fold lower than the field measurements, despite abundant gas-phase IEPOX. Sensitivity studies suggest that increasing the effective IEPOX uptake coefficient and including aerosol-phase reactions that lead to the addition of functional groups could increase the simulated IEPOX-derived aerosol mass and account for the difference between the field measurements and modeling results. |
语种 | 英语 |
WOS记录号 | WOS:000350831200002 |
来源期刊 | ENVIRONMENTAL SCIENCE & TECHNOLOGY LETTERS |
来源机构 | 美国环保署 |
文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/58577 |
作者单位 | 1.US EPA, Off Res & Dev, Res Triangle Pk, NC 27711 USA; 2.Univ N Carolina, Gillings Sch Publ Hlth, Dept Environm Sci & Engn, Chapel Hill, NC 27599 USA |
推荐引用方式 GB/T 7714 | Karambelas, Alexandra,Pye, Havala O. T.,Budisulistiorini, Sri H.,et al. Contribution of Isoprene Epoxydiol to Urban Organic Aerosol: Evidence from Modeling and Measurements[J]. 美国环保署,2014,1(6):278-283. |
APA | Karambelas, Alexandra,Pye, Havala O. T.,Budisulistiorini, Sri H.,Surratt, Jason D.,&Pinder, Robert W..(2014).Contribution of Isoprene Epoxydiol to Urban Organic Aerosol: Evidence from Modeling and Measurements.ENVIRONMENTAL SCIENCE & TECHNOLOGY LETTERS,1(6),278-283. |
MLA | Karambelas, Alexandra,et al."Contribution of Isoprene Epoxydiol to Urban Organic Aerosol: Evidence from Modeling and Measurements".ENVIRONMENTAL SCIENCE & TECHNOLOGY LETTERS 1.6(2014):278-283. |
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