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DOI10.1002/etc.2529
STABILITY AND AGGREGATION OF SILVER AND TITANIUM DIOXIDE NANOPARTICLES IN SEAWATER: ROLE OF SALINITY AND DISSOLVED ORGANIC CARBON
Wang, Huanhua1,2; Burgess, Robert M.3; Cantwell, Mark G.3; Portis, Lisa M.3; Perron, Monique M.4; Wu, Fengchang2; Ho, Kay T.3
发表日期2014-05-01
ISSN0730-7268
卷号33期号:5页码:1023-1029
英文摘要

The behavior and fate of nanoparticles (NPs) in the marine environment are largely unknown and potentially have important environmental and human health implications. The aggregation and fate of NPs in the marine environment are greatly influenced by their interactions with seawater and dissolved organic carbon (DOC). In the present study, the stability and aggregation of 30-nm-diameter silver nanoparticles (AgNPs) capped with citrate and polyvinylpyrrolidone (PVP; AgNP-citrate and AgNP-PVP) and 21-nm-diameter titanium dioxide (TiO2) NPs as affected by seawater salinity and DOC were investigated by measuring hydrodynamic diameters and zeta potentials. The added DOC (in humic acid form) stabilized the 3 types of NPs when the seawater salinities were 5 parts per thousand (ppt), but the stabilizing effect of DOC was reduced by a higher salinity (e.g., 30 ppt). In addition, AgNP-PVP was more stable than AgNP-citrate in seawater, indicating that surface capping agents and stabilization mechanisms govern the stability and aggregation of NPs. Statistical analysis showed that salinity is the most dominant influence on the stability and aggregation of AgNPs and TiO(2)NPs, followed by DOC. These findings expand our knowledge on the behavior of AgNPs and TiO(2)NPs in seawater and indicate that the fate of these NPs will be primarily to aggregate in the water column, precipitate, and accumulate in sediments following release into the marine environment. Environ Toxicol Chem 2014;33:1023-1029. (c) 2014 SETAC


英文关键词Stability;Silver;Titanium dioxide;Nanoparticle;Seawater
语种英语
WOS记录号WOS:000334488700010
来源期刊ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY
来源机构美国环保署
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/58387
作者单位1.US EPA, Natl Res Council, Off Res & Dev, Narragansett, RI USA;
2.Chinese Res Inst Environm Sci, State Key Lab Environm Criteria & Risk Assessment, Beijing, Peoples R China;
3.US EPA, Off Res & Dev, Narragansett, RI USA;
4.US EPA, Off Pesticide Programs, Washington, DC 20460 USA
推荐引用方式
GB/T 7714
Wang, Huanhua,Burgess, Robert M.,Cantwell, Mark G.,et al. STABILITY AND AGGREGATION OF SILVER AND TITANIUM DIOXIDE NANOPARTICLES IN SEAWATER: ROLE OF SALINITY AND DISSOLVED ORGANIC CARBON[J]. 美国环保署,2014,33(5):1023-1029.
APA Wang, Huanhua.,Burgess, Robert M..,Cantwell, Mark G..,Portis, Lisa M..,Perron, Monique M..,...&Ho, Kay T..(2014).STABILITY AND AGGREGATION OF SILVER AND TITANIUM DIOXIDE NANOPARTICLES IN SEAWATER: ROLE OF SALINITY AND DISSOLVED ORGANIC CARBON.ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY,33(5),1023-1029.
MLA Wang, Huanhua,et al."STABILITY AND AGGREGATION OF SILVER AND TITANIUM DIOXIDE NANOPARTICLES IN SEAWATER: ROLE OF SALINITY AND DISSOLVED ORGANIC CARBON".ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY 33.5(2014):1023-1029.
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