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DOI10.1021/acs.est.5b01657
Impact of Enhanced Ozone Deposition and Halogen Chemistry on Tropospheric Ozone over the Northern Hemisphere
Sarwar, Golam1; Gantt, Brett1; Schwede, Donna1; Foley, Kristen1; Mathur, Rohit1; Saiz-Lopez, Alfonso2
发表日期2015-08-04
ISSN0013-936X
卷号49期号:15页码:9203-9211
英文摘要

Fate of ozone in marine environments has been receiving increased attention due to the tightening of ambient air quality standards. The role of deposition and halogen chemistry is examined through incorporation of an enhanced ozone deposition algorithm and inclusion of halogen chemistry in a comprehensive atmospheric modeling system. The enhanced ozone deposition treatment accounts for the interaction of iodide in seawater with ozone and increases deposition velocities by 1 order of magnitude. Halogen chemistry includes detailed chemical reactions of organic and inorganic bromine and iodine species. Two different simulations are completed with the halogen chemistry: without and with photochemical reactions of higher iodine oxides. Enhanced deposition reduces mean summer-time surface ozone by similar to 3% over marine regions in the Northern Hemisphere. Halogen chemistry without the photochemical reactions of higher iodine oxides reduces surface ozone by similar to 15% whereas simulations with the photochemical reactions of higher iodine oxides indicate ozone reductions of similar to 48%. The model without these processes overpredicts ozone compared to observations whereas the inclusion of these processes improves predictions. The inclusion of photochemical reactions for higher iodine oxides leads to ozone predictions that are lower than observations, underscoring the need for further refinement of the halogen emissions and chemistry scheme in the model.


语种英语
WOS记录号WOS:000359278400033
来源期刊ENVIRONMENTAL SCIENCE & TECHNOLOGY
来源机构美国环保署
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/57969
作者单位1.Environm Protect Agcy, Natl Exposure Res Lab, Res Triangle Pk, NC 27711 USA;
2.CSIC, Inst Phys Chem Rocasolano, Atmospher Chem & Climate Grp, E-28006 Madrid, Spain
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GB/T 7714
Sarwar, Golam,Gantt, Brett,Schwede, Donna,et al. Impact of Enhanced Ozone Deposition and Halogen Chemistry on Tropospheric Ozone over the Northern Hemisphere[J]. 美国环保署,2015,49(15):9203-9211.
APA Sarwar, Golam,Gantt, Brett,Schwede, Donna,Foley, Kristen,Mathur, Rohit,&Saiz-Lopez, Alfonso.(2015).Impact of Enhanced Ozone Deposition and Halogen Chemistry on Tropospheric Ozone over the Northern Hemisphere.ENVIRONMENTAL SCIENCE & TECHNOLOGY,49(15),9203-9211.
MLA Sarwar, Golam,et al."Impact of Enhanced Ozone Deposition and Halogen Chemistry on Tropospheric Ozone over the Northern Hemisphere".ENVIRONMENTAL SCIENCE & TECHNOLOGY 49.15(2015):9203-9211.
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