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DOI | 10.1021/acs.est.5b01657 |
Impact of Enhanced Ozone Deposition and Halogen Chemistry on Tropospheric Ozone over the Northern Hemisphere | |
Sarwar, Golam1; Gantt, Brett1; Schwede, Donna1; Foley, Kristen1; Mathur, Rohit1; Saiz-Lopez, Alfonso2 | |
发表日期 | 2015-08-04 |
ISSN | 0013-936X |
卷号 | 49期号:15页码:9203-9211 |
英文摘要 | Fate of ozone in marine environments has been receiving increased attention due to the tightening of ambient air quality standards. The role of deposition and halogen chemistry is examined through incorporation of an enhanced ozone deposition algorithm and inclusion of halogen chemistry in a comprehensive atmospheric modeling system. The enhanced ozone deposition treatment accounts for the interaction of iodide in seawater with ozone and increases deposition velocities by 1 order of magnitude. Halogen chemistry includes detailed chemical reactions of organic and inorganic bromine and iodine species. Two different simulations are completed with the halogen chemistry: without and with photochemical reactions of higher iodine oxides. Enhanced deposition reduces mean summer-time surface ozone by similar to 3% over marine regions in the Northern Hemisphere. Halogen chemistry without the photochemical reactions of higher iodine oxides reduces surface ozone by similar to 15% whereas simulations with the photochemical reactions of higher iodine oxides indicate ozone reductions of similar to 48%. The model without these processes overpredicts ozone compared to observations whereas the inclusion of these processes improves predictions. The inclusion of photochemical reactions for higher iodine oxides leads to ozone predictions that are lower than observations, underscoring the need for further refinement of the halogen emissions and chemistry scheme in the model. |
语种 | 英语 |
WOS记录号 | WOS:000359278400033 |
来源期刊 | ENVIRONMENTAL SCIENCE & TECHNOLOGY
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来源机构 | 美国环保署 |
文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/57969 |
作者单位 | 1.Environm Protect Agcy, Natl Exposure Res Lab, Res Triangle Pk, NC 27711 USA; 2.CSIC, Inst Phys Chem Rocasolano, Atmospher Chem & Climate Grp, E-28006 Madrid, Spain |
推荐引用方式 GB/T 7714 | Sarwar, Golam,Gantt, Brett,Schwede, Donna,et al. Impact of Enhanced Ozone Deposition and Halogen Chemistry on Tropospheric Ozone over the Northern Hemisphere[J]. 美国环保署,2015,49(15):9203-9211. |
APA | Sarwar, Golam,Gantt, Brett,Schwede, Donna,Foley, Kristen,Mathur, Rohit,&Saiz-Lopez, Alfonso.(2015).Impact of Enhanced Ozone Deposition and Halogen Chemistry on Tropospheric Ozone over the Northern Hemisphere.ENVIRONMENTAL SCIENCE & TECHNOLOGY,49(15),9203-9211. |
MLA | Sarwar, Golam,et al."Impact of Enhanced Ozone Deposition and Halogen Chemistry on Tropospheric Ozone over the Northern Hemisphere".ENVIRONMENTAL SCIENCE & TECHNOLOGY 49.15(2015):9203-9211. |
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