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DOI | 10.1016/j.atmosenv.2016.06.019 |
Characterization of organophosphorus flame retardants' sorption on building materials and consumer products | |
Liu, Xiaoyu1; Allen, Matthew R.2; Roache, Nancy F.3 | |
发表日期 | 2016-09-01 |
ISSN | 1352-2310 |
卷号 | 140页码:333-341 |
英文摘要 | Better understanding the transport mechanisms of organophosphorus flame-retardants (OPFRs) in the residential environment is important to more accurately estimate their indoor exposure and develop risk management strategies that protect human health. This study describes an improved dual small chamber testing method to characterize the sorption of OPFRs on indoor building materials and consumer products. The OPFRs studied were tris(2-chloroethyl) phosphate (TCEP), tris(1-chloro-2-propyl) phosphate (TCIPP), and tris(1,3-dichloro-2-propyl) phosphate (TDCIPP). The test materials and products used as sinks include concrete, ceiling tile, vinyl flooring, carpet, latex painted gypsum wallboard, open cell polyurethane foam, mattress pad and liner, polyester clothing, cotton clothing, and uniform shirt. During the tests, the amount of OPFRs absorbed by the materials at different exposure times was determined simultaneously. OPFRs air concentrations at the inlet and inside the test chamber were monitored. The data were used to rank the sorption strength of the OPFRs on different materials. In general, building materials exhibited relatively stronger sorption strength than clothing textiles. The material-air partition and material phase diffusion coefficients were estimated by fitting a sink model to the sorption concentration data for twelve materials with three OPFRs. They are in the range of 2.72 x 10(5) to 3.99 x 10(5) (dimensionless) for the material-air partition coefficients and 1.13 x 10(-14) to 5.83 x 10(-9) (m(2)/h) for the material phase diffusion coefficients. Published by Elsevier Ltd. |
英文关键词 | Organophosphorus flame retardants;Material-air partition coefficient;Material-phase diffusion coefficient;Sink;Sorption strength |
语种 | 英语 |
WOS记录号 | WOS:000380083200029 |
来源期刊 | ATMOSPHERIC ENVIRONMENT |
来源机构 | 美国环保署 |
文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/57695 |
作者单位 | 1.US EPA, Off Res & Dev, Natl Risk Management Res Lab, Res Triangle Pk, NC 27711 USA; 2.Jacobs Technol Inc, 600 William Northern Blvd, Tullahoma, TN 37388 USA; 3.ARCADIS US Inc, 4915 Prospectus Dr,Suite F, Durham, NC 27713 USA |
推荐引用方式 GB/T 7714 | Liu, Xiaoyu,Allen, Matthew R.,Roache, Nancy F.. Characterization of organophosphorus flame retardants' sorption on building materials and consumer products[J]. 美国环保署,2016,140:333-341. |
APA | Liu, Xiaoyu,Allen, Matthew R.,&Roache, Nancy F..(2016).Characterization of organophosphorus flame retardants' sorption on building materials and consumer products.ATMOSPHERIC ENVIRONMENT,140,333-341. |
MLA | Liu, Xiaoyu,et al."Characterization of organophosphorus flame retardants' sorption on building materials and consumer products".ATMOSPHERIC ENVIRONMENT 140(2016):333-341. |
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