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DOI10.1111/ina.12093
A test house study of pesticides and pesticide degradation products following an indoor application
Starr, J. M.1; Gemma, A. A.2,3; Graham, S. E.4; Stout, D. M., II1
发表日期2014-08-01
ISSN0905-6947
卷号24期号:4页码:390-402
英文摘要

Preexisting pesticide degradates are a concern for pesticide biomonitoring studies as exposure to them may result in overestimation of pesticide exposure. The purpose of this research was to determine whether there was significant formation and movement, of pesticide degradates over a 5-week period in a controlled indoor setting after insecticide application. Movement of the pesticides during the study was also evaluated. In a simulated crack and crevice application, commercially available formulations of fipronil, propoxur, cis/trans-permethrin, and cypermethrin were applied to a series of wooden slats affixed to the wall in one room of an unoccupied test house. Floor surface samples were collected through 35 days post-application. Concentrations of the pesticides and the following degradates were determined: 2-iso-propoxyphenol, cis/trans 3-(2,2-dichlorovinyl)-3-3-dimethyl-(1-cyclopropane) carboxylic acid, 3-phenoxybenzoic acid, fipronil sulfone, fipronil sulfide, and fipronil desulfinyl. Deltamethrin, which had never been applied, and chlorpyrifos, which had been applied several years earlier, and their degradation products, cis-3-(2,2-dibromovinyl)- 2,2-dimethylcyclopropane-1-carboxylic acid, and, 3,5,6-trichloro- 2-pyridinol, respectively, were also measured. Propoxur was the only insecticide with mass movement away from the application site. There was no measurable formation or movement of the degradates. However, all degradates were present at low levels in the formulated product. These results indicate longitudinal repetitive sampling of indoor degradate levels during short-term studies, is unnecessary.


英文关键词Pyrethroids;Fipronil;Propoxur;Indoor;Degradation
语种英语
WOS记录号WOS:000339617900006
来源期刊INDOOR AIR
来源机构美国环保署
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/57655
作者单位1.US EPA, Human Exposure & Atmospher Sci Div, Natl Exposure Res Lab, Off Res & Dev, Res Triangle Pk, NC 27711 USA;
2.Natl Caucus, Washington, DC USA;
3.Ctr Black Aged SEE Program, Washington, DC USA;
4.US EPA, Hlth & Environm Impacts Div, Off Air Qual Planning & Stand, Res Triangle Pk, NC 27711 USA
推荐引用方式
GB/T 7714
Starr, J. M.,Gemma, A. A.,Graham, S. E.,et al. A test house study of pesticides and pesticide degradation products following an indoor application[J]. 美国环保署,2014,24(4):390-402.
APA Starr, J. M.,Gemma, A. A.,Graham, S. E.,&Stout, D. M., II.(2014).A test house study of pesticides and pesticide degradation products following an indoor application.INDOOR AIR,24(4),390-402.
MLA Starr, J. M.,et al."A test house study of pesticides and pesticide degradation products following an indoor application".INDOOR AIR 24.4(2014):390-402.
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