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DOI | 10.1016/j.envpol.2013.10.011 |
Silicon impurity release and surface transformation of TiO2 anatase and rutile nanoparticles in water environments | |
Liu, Xuyang1; Chen, Gexin1; Erwin, Justin G.2; Su, Chunming3 | |
发表日期 | 2014 |
ISSN | 0269-7491 |
卷号 | 184页码:570-578 |
英文摘要 | Surface transformation can affect the stability, reactivity, and toxicity of titanium dioxide (TiO2) nanoparticles (NPs) in water environments. Herein, we investigated the release kinetics of Si impurity frequently introduced during NP synthesis and the resulting effect on TiO2 NP transformation in aqueous solutions. The release of Si increased from 2 h to 19 d at three pHs with the order: pH 11.2 >= pH 2.4 > pH 8.2. The Si release process followed parabolic kinetics which is similar to diffusion controlled dissolution of minerals, and the release magnitude followed the order: 10 x 40 nm rutile > 50 nm anatase > 30 x 40 nm rutile. FTIR data indicated preferential dissolving of less polymerized Si species on NP surface. Surface potential and particle size of TiO2 NPs remained almost constant during the 42-day monitoring, implying the unaffected stability and transport of these NPs by the incongruent dissolution of impurities. (C) 2013 Elsevier Ltd. All rights reserved. |
英文关键词 | TiO2 nanoparticles;Impurity release;Transformation;Silicon;Incongruent dissolution |
语种 | 英语 |
WOS记录号 | WOS:000329419200072 |
来源期刊 | ENVIRONMENTAL POLLUTION
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来源机构 | 美国环保署 |
文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/57459 |
作者单位 | 1.CNR, Ada, OK 74820 USA; 2.E Cent Univ, Coll Hlth & Sci, Dept Chem, Ada, OK 74820 USA; 3.US EPA, Ground Water & Ecosyst Restorat Div, Natl Risk Management Res Lab, Off Res & Dev, Ada, OK 74820 USA |
推荐引用方式 GB/T 7714 | Liu, Xuyang,Chen, Gexin,Erwin, Justin G.,et al. Silicon impurity release and surface transformation of TiO2 anatase and rutile nanoparticles in water environments[J]. 美国环保署,2014,184:570-578. |
APA | Liu, Xuyang,Chen, Gexin,Erwin, Justin G.,&Su, Chunming.(2014).Silicon impurity release and surface transformation of TiO2 anatase and rutile nanoparticles in water environments.ENVIRONMENTAL POLLUTION,184,570-578. |
MLA | Liu, Xuyang,et al."Silicon impurity release and surface transformation of TiO2 anatase and rutile nanoparticles in water environments".ENVIRONMENTAL POLLUTION 184(2014):570-578. |
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