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DOI10.1080/03067319.2013.803545
Secondary organic aerosol characterisation at field sites across the United States during the spring-summer period
Lewandowski, Michael1; Piletic, Ivan R.1; Kleindienst, Tadeusz E.1; Offenberg, John H.1; Beaver, Melinda R.1; Jaoui, Mohammed2; Docherty, Kenneth S.2; Edney, Edward O.1
发表日期2013-08-01
ISSN0306-7319
卷号93期号:10页码:1084-1103
英文摘要

Sources of secondary organic carbon at 15 field sites across the United States (U.S.) during the years 2003-2010 have been examined. Filter samples have been taken for 24-h at a site in Research Triangle Park, NC; at SEARCH sites in southeastern U.S. during May and August 2005; at LADCO sites from Mar 2004-Feb 2005; Riverside, CA during SOAR in 2005; Cleveland, OH during CMAPS; and Pasadena and Bakersfield, CA during CalNex (see text for acronyms.) Samples were extracted, derivatised, and analysed for organic tracers by GC-MS. The mass fraction method described by Kleindienst et al. was used to determine the contributions of the tracers to secondary organic carbon mass. Secondary organic aerosol masses were determined using laboratory-derived values for the organic mass-organic carbon (OM/OC) ratio. Results from the analysis show secondary organic carbon in the eastern and midwestern U.S. to be consistently dominated by SOA from biogenic emissions during the spring-summer period. SOA from biogenic emissions are far less important in the western U.S. during the same period with isoprene emissions being particularly weak. These sites in the western U.S. are in more densely populated, polluted regions of California and are probably not representative of sites in the rural western U.S. The ratio of tracers from monoterpenes can also provide information regarding presumed sources. Similarly, the ratio of isoprene tracers can provide information on reaction pathways (NOX vs. non-NOX) leading to the formation of SOA in the atmosphere. Updated tables for the identity and fragmentation of SOA molecular tracers and for mass fractions of four biogenic class types (isoprene, monoterpenes, sesquiterpenes, 2-methyl-3-buten-2-ol) and two anthropogenic class types (aromatic hydrocarbons and 2-ring PAHs) are given.


英文关键词molecular tracers;secondary organic aerosol (SOA);secondary source apportionment;US field sites
语种英语
WOS记录号WOS:000324000100005
来源期刊INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY
来源机构美国环保署
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/56880
作者单位1.US EPA, Natl Exposure Res Lab, Res Triangle Pk, NC 27711 USA;
2.Alion Sci & Technol, Res Triangle Pk, NC USA
推荐引用方式
GB/T 7714
Lewandowski, Michael,Piletic, Ivan R.,Kleindienst, Tadeusz E.,et al. Secondary organic aerosol characterisation at field sites across the United States during the spring-summer period[J]. 美国环保署,2013,93(10):1084-1103.
APA Lewandowski, Michael.,Piletic, Ivan R..,Kleindienst, Tadeusz E..,Offenberg, John H..,Beaver, Melinda R..,...&Edney, Edward O..(2013).Secondary organic aerosol characterisation at field sites across the United States during the spring-summer period.INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY,93(10),1084-1103.
MLA Lewandowski, Michael,et al."Secondary organic aerosol characterisation at field sites across the United States during the spring-summer period".INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY 93.10(2013):1084-1103.
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