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DOI10.1016/j.atmosenv.2016.06.072
Technical note: Examining ozone deposition over seawater
Sarwar, Golam1; Kang, Daiwen1; Foley, Kristen1; Schwede, Donna1; Gantt, Brett2; Mathur, Rohit1
发表日期2016-09-01
ISSN1352-2310
卷号141页码:255-262
英文摘要

Surface layer resistance plays an important role in determining ozone deposition velocity over sea-water and can be influenced by chemical interactions at the air-water interface. Here, we examine the effect of chemical interactions of iodide, dimethylsulfide, dissolved organic carbon, and bromide in seawater on ozone deposition. We perform a series of simulations using the hemispheric Community Multiscale Air Quality model for summer months in the Northern Hemisphere. Our results suggest that each chemical interaction enhances the ozone deposition velocity and decreases the atmospheric ozone mixing ratio over seawater. Iodide enhances the median deposition velocity over seawater by 0.023 cm s(-1), dissolved organic carbon by 0.021 cm s(-1), dimethylsulfide by 0.002 cm s(-1), and bromide by similar to 0.0006 cm s(-1). Consequently, iodide decreases the median atmospheric ozone mixing ratio over seawater by 0.7 ppb, dissolved organic carbon by 0.8 ppb, dimethylsulfide by 0.1 ppb, and bromide by 0.02 ppb. In a separate model simulation, we account for the effect of dissolved salts in seawater on the Henry's law constant for ozone and find that it reduces the median deposition velocity by 0.007 cm s(-1) and increases surface ozone mixing ratio by 0.2 ppb. The combined effect of these processes increases the median ozone deposition velocity over seawater by 0.040 cm s(-1), lowers the atmospheric ozone mixing ratio by 5%, and slightly improves model performance relative to observations. Published by Elsevier Ltd.


英文关键词Iodide;Dimethylsulfide;Dissolved organic carbon;Ozone;Deposition
语种英语
WOS记录号WOS:000381950900023
来源期刊ATMOSPHERIC ENVIRONMENT
来源机构美国环保署
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/56598
作者单位1.US EPA, Natl Exposure Res Lab, Res Triangle Pk, NC 27711 USA;
2.US EPA, Off Air Qual Planning & Stand, Res Triangle Pk, NC USA
推荐引用方式
GB/T 7714
Sarwar, Golam,Kang, Daiwen,Foley, Kristen,et al. Technical note: Examining ozone deposition over seawater[J]. 美国环保署,2016,141:255-262.
APA Sarwar, Golam,Kang, Daiwen,Foley, Kristen,Schwede, Donna,Gantt, Brett,&Mathur, Rohit.(2016).Technical note: Examining ozone deposition over seawater.ATMOSPHERIC ENVIRONMENT,141,255-262.
MLA Sarwar, Golam,et al."Technical note: Examining ozone deposition over seawater".ATMOSPHERIC ENVIRONMENT 141(2016):255-262.
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