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DOI | 10.1016/j.chroma.2013.07.017 |
Rapid liquid chromatography-tandem mass spectrometry-based method for the analysis of alcohol ethoxylates and alkylphenol ethoxylates in environmental samples | |
DeArmond, Patrick D.1; DiGoregorio, Amanda L.2 | |
发表日期 | 2013-08-30 |
ISSN | 0021-9673 |
卷号 | 1305页码:154-163 |
英文摘要 | A sensitive and selective method for the determination of alcohol ethoxylates (AEOs) and alkylphenol ethoxylates (APEOs) using solid-phase extraction (SPE) and LC-MS/MS was developed and applied to the analysis of water samples. All AEO and APEO homologues, a total of 152 analytes, were analyzed within a run time of 11 min, and the MS allowed for the detection of ethoxymers containing 2-20 ethoxy units (eta(EO) = 2-20). The limits of detection (LOD) were as low as 0.1 pg injected, which generally increased as eta(EO) increased (e.g., as high as 300 pg for eta(EO) =20). Additionally, the responses of the various ethoxymers varied by orders of magnitude, with ethoxymers with eta(EO) = 3-5 being the most sensitive and those with eta(EO) > 15 producing the least response in the MS. Absolute extraction recoveries of the analytes ranged from 37% to 69% in ultrapure water (RSD <= 20%), with the recovery depending on the length of the alkyl chain. Abiotic stability studies were performed, and C14-18 ethoxylates showed significant degrees of degradation. Water samples from the Colorado River were then analyzed for AEOs and APEOs, with absolute extraction recoveries ranging from 33% to 45% (RSD <= 12%). The predominant species observed in most samples were the octylphenol (OP) and nonylphenol (NP) ethoxylates, which contained total concentrations that were greater than 100 ng/L APEOs in a couple samples. Other AEO homologues were identified in the river water samples, including C-13, C-16, C-16, and C-18 ethoxylates, but these compounds. were generally present at much lower levels (i.e., <50 ng/L total concentration). Published by Elsevier B.V. |
英文关键词 | Liquid chromatography-tandem mass spectrometry;Alcohol ethoxylates;Alkylphenol ethoxylates;Solid-phase extraction;Nonionic surfactants |
语种 | 英语 |
WOS记录号 | WOS:000323362200020 |
来源期刊 | JOURNAL OF CHROMATOGRAPHY A
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来源机构 | 美国环保署 |
文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/56460 |
作者单位 | 1.USA Environm Protect Agcy, Off Res & Dev, Natl Exposure Lab, Div Environm Sci, Las Vegas, NV 89119 USA; 2.USA Environm Protect Agcy, Las Vegas, NV 89119 USA |
推荐引用方式 GB/T 7714 | DeArmond, Patrick D.,DiGoregorio, Amanda L.. Rapid liquid chromatography-tandem mass spectrometry-based method for the analysis of alcohol ethoxylates and alkylphenol ethoxylates in environmental samples[J]. 美国环保署,2013,1305:154-163. |
APA | DeArmond, Patrick D.,&DiGoregorio, Amanda L..(2013).Rapid liquid chromatography-tandem mass spectrometry-based method for the analysis of alcohol ethoxylates and alkylphenol ethoxylates in environmental samples.JOURNAL OF CHROMATOGRAPHY A,1305,154-163. |
MLA | DeArmond, Patrick D.,et al."Rapid liquid chromatography-tandem mass spectrometry-based method for the analysis of alcohol ethoxylates and alkylphenol ethoxylates in environmental samples".JOURNAL OF CHROMATOGRAPHY A 1305(2013):154-163. |
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