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| DOI | 10.1021/acs.est.4c02600 |
| Isotope Data Constrains Redox Chemistry of Atmospheric Mercury | |
| 发表日期 | 2024 |
| ISSN | 0013-936X |
| EISSN | 1520-5851 |
| 英文摘要 | The redox chemistry of mercury (Hg) in the atmosphere exerts a significant influence on its global cycle. However, our understanding of this important process remains shrouded in uncertainty. In this study, we utilize three-dimensional atmospheric Hg isotope modeling to evaluate the isotopic composition of particle-bound mercury [Hg-II(P)] in the global atmosphere. We investigate various chemistry mechanisms and find that they induce remarkably disparate odd-number mass-independent fractionation (odd-MIF) in Hg-II(P) on a global scale. The observed odd-MIF data identify the essential role of sea salt aerosol debromination in the redox chemistry of atmospheric Hg and underscore the predominant influence of Br oxidation in the marine boundary layer. The odd-MIF signatures significantly narrow the uncertainty range of redox chemistry rates and constrain the photoreduction of Hg-II(P) at a magnitude of 10(-3) JNO(2) (local photolysis frequency of NO2) in the global atmosphere. This study advances our understanding of atmospheric Hg chemistry processes and provides insights into the potential impacts of climate change on Hg cycling. |
| 英文关键词 | atmosphere mercury chemistry; mercury isotope; isotope model; particle-bound mercury; GEOS-Chem |
| 语种 | 英语 |
| WOS研究方向 | Engineering ; Environmental Sciences & Ecology |
| WOS类目 | Engineering, Environmental ; Environmental Sciences |
| WOS记录号 | WOS:001235215800001 |
| 来源期刊 | ENVIRONMENTAL SCIENCE & TECHNOLOGY
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| 文献类型 | 期刊论文 |
| 条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/293611 |
| 作者单位 | Nanjing University; Nanjing University |
| 推荐引用方式 GB/T 7714 | . Isotope Data Constrains Redox Chemistry of Atmospheric Mercury[J],2024. |
| APA | (2024).Isotope Data Constrains Redox Chemistry of Atmospheric Mercury.ENVIRONMENTAL SCIENCE & TECHNOLOGY. |
| MLA | "Isotope Data Constrains Redox Chemistry of Atmospheric Mercury".ENVIRONMENTAL SCIENCE & TECHNOLOGY (2024). |
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