气候变化领域集成服务门户(CCPortal): Grafting-from Synthesis of Plant-Polynorbornene Biohybrid Materials

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DOI	10.1021/acsmacrolett.4c00297
	Grafting-from Synthesis of Plant-Polynorbornene Biohybrid Materials
	Palomino, Luis; Gonzalez-Gamboa, Ivonne; Garcia-Mendoza, Moises; Monroy-Borrego, Andrea G.; Tang, Lisa; Wang, Bin; Tao, Andrea; Bae, Jinhye; Steinmetz, Nicole F.; Pokorski, Jonathan K.
发表日期	2024
EISSN	2161-1653
英文摘要	Plants, essential for food, oxygen, and economic stability, are under threat from human activities, biotic threats, and climate change, requiring rapid technological advancements for protection. Biohybrid systems, merging synthetic macromolecules with biological components, have provided improvement to biological systems in the past, namely, in the biomedical arena, motivating an opportunity to enhance plant well-being. Nevertheless, strategies for plant biohybrid systems remain limited. In this study, we present a method using grafting-from ring-opening metathesis polymerization (ROMP) under physiological conditions to integrate norbornene-derived polymers into live plants by spray coating. The approach involves creating biological macroinitiators on leaf surfaces, which enable subsequent polymerization of norbornene-derived monomers. Characterization techniques, including FTIR spectroscopy, SEM EDS imaging, ICP-MS, nanoindentation, and XPS, confirmed the presence and characterized the properties of the polymeric layers on leaves. The demonstrated modifiability and biocompatibility could offer the potential to maintain plant health in various applications, including the development of thermal barriers, biosensors, and crop protection layers.
语种	英语
WOS研究方向	Polymer Science
WOS类目	Polymer Science
WOS记录号	WOS:001235226500001
来源期刊	ACS MACRO LETTERS
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/292047
作者单位	University of California System; University of California San Diego; University of California System; University of California San Diego; University of California System; University of California San Diego; University of California System; University of California San Diego; University of California System; University of California San Diego; University of California System; University of California San Diego; University of California System; University of California San Diego
推荐引用方式 GB/T 7714	Palomino, Luis,Gonzalez-Gamboa, Ivonne,Garcia-Mendoza, Moises,et al. Grafting-from Synthesis of Plant-Polynorbornene Biohybrid Materials[J],2024.
APA	Palomino, Luis.,Gonzalez-Gamboa, Ivonne.,Garcia-Mendoza, Moises.,Monroy-Borrego, Andrea G..,Tang, Lisa.,...&Pokorski, Jonathan K..(2024).Grafting-from Synthesis of Plant-Polynorbornene Biohybrid Materials.ACS MACRO LETTERS.
MLA	Palomino, Luis,et al."Grafting-from Synthesis of Plant-Polynorbornene Biohybrid Materials".ACS MACRO LETTERS (2024).