气候变化领域集成服务门户(CCPortal): Thermo-, Electro-, and Photocatalytic CO2 Conversion to Value- Added Products over Porous Metal/Covalent Organic Frameworks

CCPortal

DOI	10.1021/acs.accounts.2c00326
	Thermo-, Electro-, and Photocatalytic CO2 Conversion to Value- Added Products over Porous Metal/Covalent Organic Frameworks
	Wu, Qiu-Jin; Liang, Jun; Huang, Yuan-Biao; Cao, Rong
发表日期	2022
ISSN	0001-4842
EISSN	1520-4898
起始页码	2978
结束页码	2997
卷号	55 期号:20
英文摘要	CONSPECTUS: The continuing increase of the concentration of atmospheric CO2 has caused many environmental issues including climate change. Catalytic conversion of CO2 using thermochemical, electrochemical, and photochemical methods is a potential technique to decrease the CO2 concentration and simultaneously obtain value-added chemicals. Due to the high energy barrier of CO2 however, this method is still far from large-scale applications which requires high activity, selectivity, and stability. Therefore, development of efficient catalysts to convert CO2 to different products is urgent. With their well-engineered pores and chemical compositions, high surface area, elevated CO2 adsorption capability, and adjustable active sites, porous crystalline frameworks including metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) are potential materials for catalytic CO2 conversion. Here, we summarize our recent work on MOFs and COFs for thermocatalytic, electrocatalytic, and photocatalytic CO2 conversion and describe the structure-activity relationships that could guide the design of effective catalysts. The first section of this paper describes imidazolium-functionalized porous MOFs, including porous liquid and cationic MOFs with nucleophilic halogen ions, which can promote thermocatalytically CO2 cycloaddition reaction with epoxides toward cyclic carbonates at one bar pressure. A porous liquid MOF takes on the role of a CO2 reservoir to tackle the low local CO2 concentrations in gas-liquid-solid heterogeneous reactions. Imidazolium-functionalized MOFs with halogen ions for CO2 cycloaddition could avoid the use of cocatalysts, and this leads to milder and more facile experimental conditions and separation processes. In a section dealing with the electrocatalytic CO2 reduction reaction (CO2RR), we developed a series of conductive porous framework materials with fast electron transmission capabilities, which afford high current densities and outperform the traditional MOF and COF catalysts that have been reported. The intrinsically conductive two-dimensional 2D MOFs and COFs nanosheets based on the fully pi-conjugated phthalocyanine motif with excellent electron transport capability were prepared, and strong electron transporters were also integrated into metalloporphyrin-based COFs for CO2RR. Cu2O quantum dots and Cu nanoparticles (NPs) can be uniformly dispersed on porous conductive MOFs/COFs to afford synergistic and/or tandem electrocatalysts, which can achieve highly selective production of CH4 or C2H4 in CO2RR. A third section describes our efforts to facilitate electron-hole separation in CO2 photocatalysis. Our focus is on regulation of coordination spheres in MOFs, fabrication of the architecture of MOF heterojunctions, and engineering MOF films to facilitate photocatalytic CO2 reduction.Finally, we discuss several problems associated with the studies of MOFs and COFs for CO2 conversion and consider some prospects of the fabrication of effective porous frameworks for CO2 adsorption and conversion.
语种	英语
WOS研究方向	Chemistry, Multidisciplinary
WOS类目	Science Citation Index Expanded (SCI-EXPANDED)
WOS记录号	WOS:000867493300001
来源期刊	ACCOUNTS OF CHEMICAL RESEARCH
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/281136
作者单位	Chinese Academy of Sciences; Fujian Institute of Research on the Structure of Matter, CAS; Hebei University of Technology; Chinese Academy of Sciences; University of Chinese Academy of Sciences, CAS; Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China
推荐引用方式 GB/T 7714	Wu, Qiu-Jin,Liang, Jun,Huang, Yuan-Biao,et al. Thermo-, Electro-, and Photocatalytic CO2 Conversion to Value- Added Products over Porous Metal/Covalent Organic Frameworks[J],2022,55(20).
APA	Wu, Qiu-Jin,Liang, Jun,Huang, Yuan-Biao,&Cao, Rong.(2022).Thermo-, Electro-, and Photocatalytic CO2 Conversion to Value- Added Products over Porous Metal/Covalent Organic Frameworks.ACCOUNTS OF CHEMICAL RESEARCH,55(20).
MLA	Wu, Qiu-Jin,et al."Thermo-, Electro-, and Photocatalytic CO2 Conversion to Value- Added Products over Porous Metal/Covalent Organic Frameworks".ACCOUNTS OF CHEMICAL RESEARCH 55.20(2022).