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DOI10.1016/j.ccr.2022.214563
Porphyrin and phthalocyanine based covalent organic frameworks for electrocatalysis
Huang, Shengsheng; Chen, Kai; Li, Ting-Ting
发表日期2022
ISSN0010-8545
EISSN1873-3840
卷号464
英文摘要Covalent organic frameworks (COFs) area burgeoning class of crystalline porous polymers. Owing to their unique features including tunable porosity, abundant accessible active sites, synthetically controllability, and pre-designed topological structures, COFs have been widely employed in various fields including catalysis, energy storage and conversion, gas adsorption, and optoelectronics. The incorporation of porphyrin (Por-) and phthalocyanine (Pc-) building units into COFs endows COFs with unique structural characteristics, excellent optical and electrical properties. Recent years have witnessed significant pro-gress in reasonable design and construction of Por-and Pc-based COFs for electrocatalytic water splitting, CO2 reduction, and oxygen reduction. Herein, the synthetic strategies of Por-and Pc-based COFs are first summarized, which includes the rational design of building units and linkers, and the reaction types used in constructing Por-and Pc-based COFs. A systematic overview of the application of Por-and Pc-based COFs in the electrocatalytic reactions including CO2 reduction reaction (CO2RR), hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR) are then performed. Lastly, the current challenges and directions to tailor Por-and Pc-based COFs for efficient and stable elec-trocatalysis are presented. (C)& nbsp;2022 Elsevier B.V. All rights reserved.
英文关键词Covalent organic frameworks; Porphyrin; Phthalocyanine; Electrocatalysis; Performance
语种英语
WOS研究方向Chemistry, Inorganic & Nuclear
WOS类目Science Citation Index Expanded (SCI-EXPANDED)
WOS记录号WOS:000794149200004
来源期刊COORDINATION CHEMISTRY REVIEWS
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/280929
作者单位Ningbo University; Ningbo University
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GB/T 7714
Huang, Shengsheng,Chen, Kai,Li, Ting-Ting. Porphyrin and phthalocyanine based covalent organic frameworks for electrocatalysis[J],2022,464.
APA Huang, Shengsheng,Chen, Kai,&Li, Ting-Ting.(2022).Porphyrin and phthalocyanine based covalent organic frameworks for electrocatalysis.COORDINATION CHEMISTRY REVIEWS,464.
MLA Huang, Shengsheng,et al."Porphyrin and phthalocyanine based covalent organic frameworks for electrocatalysis".COORDINATION CHEMISTRY REVIEWS 464(2022).
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