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DOI10.1038/s41893-022-00974-w
Polymeric membranes with aligned zeolite nanosheets for sustainable energy storage
Xia, Yongsheng; Cao, Hongyan; Xu, Fang; Chen, Yuxin; Xia, Yu; Zhang, Dezhu; Dai, Liheng; Qu, Kai; Lian, Cheng; Huang, Kang; Xing, Weihong; Jin, Wanqin; Xu, Zhi
发表日期2022
ISSN2398-9629
起始页码1080
结束页码+
卷号5期号:12页码:14
英文摘要Membrane technologies with low environmental impacts and ease of use have a wide spectrum of applications, with the potential to provide more sustainable solutions in domains such as water, energy and pollution treatment. However, the design of membranes is subject to a trade-off between ion conductivity and selectivity. Here we show a composite polymeric membrane that breaks this dilemma and supports both high proton conductivity (80.1 mS cm(-1)) and good vanadium ion selectivity (2.01 x 10(5) S min cm(-3)). Underlying this synthetic success is a flow-processing technique through which zeolite nanosheet fillers are oriented in a preferred direction throughout a polymer Nafion matrix. As a result, pairing this aligned membrane with a vanadium flow battery leads to a high energy efficiency of >80% at 200 mA cm(-2) and remarkable stability over 1,000 cycles. This work enables the design of membranes that combine otherwise mutually exclusively properties for many possible applications beyond energy storage. Membranes are at the heart of various technologies for water, energy and other sustainability relevant areas. Here the authors show a synthetic route to a polymeric membrane that breaks the conductivity-selectivity trade-off and enables exciting performance in a vanadium flow battery.
学科领域Green & Sustainable Science & Technology; Environmental Sciences; Environmental Studies
语种英语
WOS研究方向Science & Technology - Other Topics ; Environmental Sciences & Ecology
WOS记录号WOS:000869351200002
来源期刊NATURE SUSTAINABILITY
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/272768
作者单位Nanjing Tech University; East China University of Science & Technology
推荐引用方式
GB/T 7714
Xia, Yongsheng,Cao, Hongyan,Xu, Fang,et al. Polymeric membranes with aligned zeolite nanosheets for sustainable energy storage[J],2022,5(12):14.
APA Xia, Yongsheng.,Cao, Hongyan.,Xu, Fang.,Chen, Yuxin.,Xia, Yu.,...&Xu, Zhi.(2022).Polymeric membranes with aligned zeolite nanosheets for sustainable energy storage.NATURE SUSTAINABILITY,5(12),14.
MLA Xia, Yongsheng,et al."Polymeric membranes with aligned zeolite nanosheets for sustainable energy storage".NATURE SUSTAINABILITY 5.12(2022):14.
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