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DOI | 10.1038/s41893-022-00974-w |
Polymeric membranes with aligned zeolite nanosheets for sustainable energy storage | |
Xia, Yongsheng; Cao, Hongyan; Xu, Fang; Chen, Yuxin; Xia, Yu; Zhang, Dezhu; Dai, Liheng; Qu, Kai; Lian, Cheng; Huang, Kang; Xing, Weihong; Jin, Wanqin; Xu, Zhi | |
发表日期 | 2022 |
ISSN | 2398-9629 |
起始页码 | 1080 |
结束页码 | + |
卷号 | 5期号:12页码:14 |
英文摘要 | Membrane technologies with low environmental impacts and ease of use have a wide spectrum of applications, with the potential to provide more sustainable solutions in domains such as water, energy and pollution treatment. However, the design of membranes is subject to a trade-off between ion conductivity and selectivity. Here we show a composite polymeric membrane that breaks this dilemma and supports both high proton conductivity (80.1 mS cm(-1)) and good vanadium ion selectivity (2.01 x 10(5) S min cm(-3)). Underlying this synthetic success is a flow-processing technique through which zeolite nanosheet fillers are oriented in a preferred direction throughout a polymer Nafion matrix. As a result, pairing this aligned membrane with a vanadium flow battery leads to a high energy efficiency of >80% at 200 mA cm(-2) and remarkable stability over 1,000 cycles. This work enables the design of membranes that combine otherwise mutually exclusively properties for many possible applications beyond energy storage. Membranes are at the heart of various technologies for water, energy and other sustainability relevant areas. Here the authors show a synthetic route to a polymeric membrane that breaks the conductivity-selectivity trade-off and enables exciting performance in a vanadium flow battery. |
学科领域 | Green & Sustainable Science & Technology; Environmental Sciences; Environmental Studies |
语种 | 英语 |
WOS研究方向 | Science & Technology - Other Topics ; Environmental Sciences & Ecology |
WOS记录号 | WOS:000869351200002 |
来源期刊 | NATURE SUSTAINABILITY |
文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/272768 |
作者单位 | Nanjing Tech University; East China University of Science & Technology |
推荐引用方式 GB/T 7714 | Xia, Yongsheng,Cao, Hongyan,Xu, Fang,et al. Polymeric membranes with aligned zeolite nanosheets for sustainable energy storage[J],2022,5(12):14. |
APA | Xia, Yongsheng.,Cao, Hongyan.,Xu, Fang.,Chen, Yuxin.,Xia, Yu.,...&Xu, Zhi.(2022).Polymeric membranes with aligned zeolite nanosheets for sustainable energy storage.NATURE SUSTAINABILITY,5(12),14. |
MLA | Xia, Yongsheng,et al."Polymeric membranes with aligned zeolite nanosheets for sustainable energy storage".NATURE SUSTAINABILITY 5.12(2022):14. |
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