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DOI10.1016/j.jpcs.2021.110475
Comparison of reidite formation between zircon bulk and nanoparticles
Nan, Shuai; Niu, Jingjing; Liang, Lin; Lu, Ziyao; Wang, Qikun; Zhai, Pengfei; Liu, Yingxin; Qin, Shan; Li, Weixing
通讯作者Li, WX (通讯作者)
发表日期2022
ISSN0022-3697
EISSN1879-2553
卷号161
英文摘要Although modifying high-pressure behavior through the particle-size of a material is well recognized, a clear mechanism, underlying the start and subsequent growth of a high-pressure phase, remains elusive. Here, we investigate the effects of particle-size on the formation of reidite (ZrSiO4, I41/a), a high-pressure phase of zircon (ZrSiO4, I41/amd), by comparing zircon nanoparticles with bulk. This is done by high pressure Raman scattering and synchrotron X-ray diffraction experiments on zircons pressurized in diamond anvil cells and subsequent transmission electron microscopy analysis of quenched samples. As compared to bulk, the larger surface energy of nanoparticles is the cause of a higher critical pressure required to start the transition to reidite. However, after passing the critical pressures, the similar growth trends between nanoparticles and bulk indicate that the reidite growth is dependent on the core, rather than the surface. These results are important to identify craters caused by meteorite impacts using reidite as a high-pressure indicator, as nanoparticles are formed in naturally-occurring, highly radiation-damaged zircon.
关键词SOLID PHASE-TRANSITIONHIGH-PRESSURESIZE DEPENDENCEZRSIO4TRANSFORMATIONSDIFFRACTIONIRRADIATIONPOLYMORPHEQUATION
英文关键词High pressure; Phase transition; Zircon; Nanoparticles; Surface energy
语种英语
WOS研究方向Chemistry ; Physics
WOS类目Chemistry, Multidisciplinary ; Physics, Condensed Matter
WOS记录号WOS:000737300100005
来源期刊JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
来源机构中国科学院青藏高原研究所
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/260725
推荐引用方式
GB/T 7714
Nan, Shuai,Niu, Jingjing,Liang, Lin,et al. Comparison of reidite formation between zircon bulk and nanoparticles[J]. 中国科学院青藏高原研究所,2022,161.
APA Nan, Shuai.,Niu, Jingjing.,Liang, Lin.,Lu, Ziyao.,Wang, Qikun.,...&Li, Weixing.(2022).Comparison of reidite formation between zircon bulk and nanoparticles.JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS,161.
MLA Nan, Shuai,et al."Comparison of reidite formation between zircon bulk and nanoparticles".JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS 161(2022).
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