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DOI	10.1039/d1cy00112d
	Efficient and stable low-temperature CO oxidation over Pt/In-SnO2 composite triggered by abundant oxygen vacancies and adsorption sites
	Sun, Yukun; Gao, Yang; He, Chi; Song, Weiyu; Jiang, Zeyu; Albilali, Reem; Bai, Bo
通讯作者	Bai, B (通讯作者)，Changan Univ, Sch Water & Environm, Minist Educ, Key Lab Subsurface Hydrol & Ecol Effects Arid Reg, Xian 710064, Peoples R China. ; He, C (通讯作者)，Xi An Jiao Tong Univ, Sch Energy & Power Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Shaanxi, Peoples R China. ; Bai, B (通讯作者)，Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810008, Peoples R China. ; Bai, B (通讯作者)，Qinghai Prov Key Lab Tibetan Med Res, Xining 810001, Peoples R China.
发表日期	2021
ISSN	2044-4753
EISSN	2044-4761
起始页码	3762
结束页码	3774
卷号	11 期号:11
英文摘要	It is of great significance to design highly active and stable catalysts for CO oxidation. Herein, a Pt/In-SnO2 catalyst was firstly fabricated via a facile hydrothermal reaction coupled with photoreduction strategy, achieving 1 vol% of CO totally oxidized at just 145 degrees C, over 200 degrees C lower than that of Pt/SnO2. Moreover, Pt/In-SnO2 demonstrates superior catalytic stability and recyclability under both dry and humid conditions. Incorporation of In cations results in marked structure distortion of SnO2, promoting the formation of oxygen vacancies and enhancing the concentration and mobility of reactive oxygen species. Abundant Pt sites over Pt/In-SnO2 further accelerate CO adsorption and activation. Density functional theory results prove that the energy barrier of CO oxidation reduces from 0.85 to 0.75 eV after In doping and the produced CO2 can desorb spontaneously from the catalyst surface, which accelerates the CO oxidation process. This work provides new ideas for designing robust catalysts for low-temperature CO elimination.
关键词	CATALYTIC-OXIDATION AU NANOPARTICLES PT/CEO2 CATALYST OXIDE SNO2 CU PERFORMANCE TOLUENE TIO2 FE
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
WOS记录号	WOS:000643921700001
来源期刊	CATALYSIS SCIENCE & TECHNOLOGY
来源机构	中国科学院西北生态环境资源研究院
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/255037
作者单位	[Sun, Yukun; Bai, Bo] Changan Univ, Sch Water & Environm, Minist Educ, Key Lab Subsurface Hydrol & Ecol Effects Arid Reg, Xian 710064, Peoples R China; [Sun, Yukun; He, Chi; Jiang, Zeyu] Xi An Jiao Tong Univ, Sch Energy & Power Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Shaanxi, Peoples R China; [Gao, Yang; Song, Weiyu] China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China; [Albilali, Reem] Imam Abdulrahman Bin Faisal Univ, Coll Sci, Dept Chem, POB 1982, Dammam 31441, Saudi Arabia; [Bai, Bo] Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810008, Peoples R China; [Bai, Bo] Qinghai Prov Key Lab Tibetan Med Res, Xining 810001, Peoples R China
推荐引用方式 GB/T 7714	Sun, Yukun,Gao, Yang,He, Chi,et al. Efficient and stable low-temperature CO oxidation over Pt/In-SnO2 composite triggered by abundant oxygen vacancies and adsorption sites[J]. 中国科学院西北生态环境资源研究院,2021,11(11).
APA	Sun, Yukun.,Gao, Yang.,He, Chi.,Song, Weiyu.,Jiang, Zeyu.,...&Bai, Bo.(2021).Efficient and stable low-temperature CO oxidation over Pt/In-SnO2 composite triggered by abundant oxygen vacancies and adsorption sites.CATALYSIS SCIENCE & TECHNOLOGY,11(11).
MLA	Sun, Yukun,et al."Efficient and stable low-temperature CO oxidation over Pt/In-SnO2 composite triggered by abundant oxygen vacancies and adsorption sites".CATALYSIS SCIENCE & TECHNOLOGY 11.11(2021).