气候变化领域集成服务门户(CCPortal): Hyperacmosin N, new acylphloroglucinol derivative with complicated caged core from Hypericum acmosepalum

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DOI	10.1016/j.tet.2021.132286
	Hyperacmosin N, new acylphloroglucinol derivative with complicated caged core from Hypericum acmosepalum
	Sun, Ming-xia; Dang, Jun; Zhu, Ting-ting; Wang, Xue; Suo, Xin-yue; Wang, Jia-jia; Ji, Teng-fei; Liu, Bo
通讯作者	Ji, TF (通讯作者)，Chinese Acad Med Sci & Peking Union Med Coll, Inst Mat Med, State Key Lab Bioact Subst & Funct Nat Med, Beijing 100050, Peoples R China. ; Liu, B (通讯作者)，Shenyang Med Coll, Sch Pharm, Shenyang 110034, Peoples R China.
发表日期	2021
ISSN	0040-4020
EISSN	1464-5416
卷号	94
英文摘要	Three new polycyclic polyprenylated acylphloroglucinol derivatives, hyperacmosins N -P (1-3), were isolated from the air-dried aerial parts of Hypericum asmosepalum. Especially, compound 1 possessed a rare hex acyclic core, which was formed via oxidation and radical cyclization. Their structures were established by NMR, HRMS (ESI), and experimental electronic circular dichroism (ECD) spectra. The plausible biogenetic pathways of 1-3 were proposed, which gave an insight for future biomimetic synthesis of the novel compounds. (c) 2021 Elsevier Ltd. All rights reserved.
关键词	POLYPRENYLATED ACYLPHLOROGLUCINOLS FRUITS
英文关键词	Hypericum acmosepalum; PPAPs; Hexacyclic skeleton; Radical cyclization
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000687139400001
来源期刊	TETRAHEDRON
来源机构	中国科学院西北生态环境资源研究院
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/254887
作者单位	[Sun, Ming-xia; Zhu, Ting-ting; Wang, Xue; Suo, Xin-yue; Wang, Jia-jia; Ji, Teng-fei] Chinese Acad Med Sci & Peking Union Med Coll, Inst Mat Med, State Key Lab Bioact Subst & Funct Nat Med, Beijing 100050, Peoples R China; [Dang, Jun] Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810008, Peoples R China; [Liu, Bo] Shenyang Med Coll, Sch Pharm, Shenyang 110034, Peoples R China
推荐引用方式 GB/T 7714	Sun, Ming-xia,Dang, Jun,Zhu, Ting-ting,et al. Hyperacmosin N, new acylphloroglucinol derivative with complicated caged core from Hypericum acmosepalum[J]. 中国科学院西北生态环境资源研究院,2021,94.
APA	Sun, Ming-xia.,Dang, Jun.,Zhu, Ting-ting.,Wang, Xue.,Suo, Xin-yue.,...&Liu, Bo.(2021).Hyperacmosin N, new acylphloroglucinol derivative with complicated caged core from Hypericum acmosepalum.TETRAHEDRON,94.
MLA	Sun, Ming-xia,et al."Hyperacmosin N, new acylphloroglucinol derivative with complicated caged core from Hypericum acmosepalum".TETRAHEDRON 94(2021).