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DOI10.1016/j.carbpol.2022.119113
Swelling and glyphosate-controlled release behavior of multi-responsive alginate-g-P(NIPAm-co-NDEAm)-based hydrogel
Zheng, Dan; Wang, Kai; Bai, Bo; Hu, Na; Wang, Honglun
通讯作者Bai, B (通讯作者),Changan Univ, Key Lab Subsurface Hydrol & Ecol Effects Arid Reg, Minist Educ, Xian 710054, Peoples R China.
发表日期2022
ISSN0144-8617
EISSN1879-1344
卷号282
英文摘要Intelligent controlled release systems (ICRS) displayed great achievement in agriculture by enhancing the uti-lization efficiency of agrochemicals. In this work, an intelligent graft copolymer (Alg-g-P(NIPAm-co-NDEAm)) with alginate (Alg) backbone and thermo-responsive poly(N-isopropyl acrylamide-co-N,N-diethylacrylamide) (P (NIPAm-co-NDEAm)) side chain was constructed as the matrix of ICRS through redox copolymerization, and its thermo-induced responsive property was studied. Then, the copolymer was mixed with a promising photo-thermal material semi-coke (SC) to form hydrogel beads (Ca-Alg-g-P(NIPAm-co-NDEAm)/SC) by ion cross-linking. The water absorbency of beads under different stimuli (pH, temperature, and light) presented outstanding responsive performance and the swelling mechanism was analyzed through coupling theory. Furthermore, the release of glyphosate (Gly) from Ca-Alg-g-P(NIPAm-co-NDEAm)/SC under environmental stimuli displayed regulatable behaviors. This multi-responsive hydrogel bead shows bright prospect in the sus-tainable advancement of crop production.
关键词COMPLEX MICELLESWATERMICROSPHERESCOMPOSITEREMOVALPNIPAM
英文关键词Sodium alginate; Controlled-release; Stimulus-response; Water-absorbent mechanism; Agrochemical
语种英语
WOS研究方向Chemistry ; Polymer Science
WOS类目Chemistry, Applied ; Chemistry, Organic ; Polymer Science
WOS记录号WOS:000782089400001
来源期刊CARBOHYDRATE POLYMERS
来源机构中国科学院西北生态环境资源研究院
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/254762
作者单位[Zheng, Dan; Bai, Bo] Changan Univ, Key Lab Subsurface Hydrol & Ecol Effects Arid Reg, Minist Educ, Xian 710054, Peoples R China; [Zheng, Dan; Bai, Bo] Changan Univ, Sch Water & Environm, Xian 710054, Peoples R China; [Wang, Kai] Beijing Normal Univ, Coll Water Sci, Beijing 100875, Peoples R China; [Bai, Bo; Hu, Na; Wang, Honglun] Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810008, Peoples R China
推荐引用方式
GB/T 7714
Zheng, Dan,Wang, Kai,Bai, Bo,et al. Swelling and glyphosate-controlled release behavior of multi-responsive alginate-g-P(NIPAm-co-NDEAm)-based hydrogel[J]. 中国科学院西北生态环境资源研究院,2022,282.
APA Zheng, Dan,Wang, Kai,Bai, Bo,Hu, Na,&Wang, Honglun.(2022).Swelling and glyphosate-controlled release behavior of multi-responsive alginate-g-P(NIPAm-co-NDEAm)-based hydrogel.CARBOHYDRATE POLYMERS,282.
MLA Zheng, Dan,et al."Swelling and glyphosate-controlled release behavior of multi-responsive alginate-g-P(NIPAm-co-NDEAm)-based hydrogel".CARBOHYDRATE POLYMERS 282(2022).
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