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DOI | 10.1016/j.carbpol.2022.119113 |
Swelling and glyphosate-controlled release behavior of multi-responsive alginate-g-P(NIPAm-co-NDEAm)-based hydrogel | |
Zheng, Dan; Wang, Kai; Bai, Bo; Hu, Na; Wang, Honglun | |
通讯作者 | Bai, B (通讯作者),Changan Univ, Key Lab Subsurface Hydrol & Ecol Effects Arid Reg, Minist Educ, Xian 710054, Peoples R China. |
发表日期 | 2022 |
ISSN | 0144-8617 |
EISSN | 1879-1344 |
卷号 | 282 |
英文摘要 | Intelligent controlled release systems (ICRS) displayed great achievement in agriculture by enhancing the uti-lization efficiency of agrochemicals. In this work, an intelligent graft copolymer (Alg-g-P(NIPAm-co-NDEAm)) with alginate (Alg) backbone and thermo-responsive poly(N-isopropyl acrylamide-co-N,N-diethylacrylamide) (P (NIPAm-co-NDEAm)) side chain was constructed as the matrix of ICRS through redox copolymerization, and its thermo-induced responsive property was studied. Then, the copolymer was mixed with a promising photo-thermal material semi-coke (SC) to form hydrogel beads (Ca-Alg-g-P(NIPAm-co-NDEAm)/SC) by ion cross-linking. The water absorbency of beads under different stimuli (pH, temperature, and light) presented outstanding responsive performance and the swelling mechanism was analyzed through coupling theory. Furthermore, the release of glyphosate (Gly) from Ca-Alg-g-P(NIPAm-co-NDEAm)/SC under environmental stimuli displayed regulatable behaviors. This multi-responsive hydrogel bead shows bright prospect in the sus-tainable advancement of crop production. |
关键词 | COMPLEX MICELLESWATERMICROSPHERESCOMPOSITEREMOVALPNIPAM |
英文关键词 | Sodium alginate; Controlled-release; Stimulus-response; Water-absorbent mechanism; Agrochemical |
语种 | 英语 |
WOS研究方向 | Chemistry ; Polymer Science |
WOS类目 | Chemistry, Applied ; Chemistry, Organic ; Polymer Science |
WOS记录号 | WOS:000782089400001 |
来源期刊 | CARBOHYDRATE POLYMERS |
来源机构 | 中国科学院西北生态环境资源研究院 |
文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/254762 |
作者单位 | [Zheng, Dan; Bai, Bo] Changan Univ, Key Lab Subsurface Hydrol & Ecol Effects Arid Reg, Minist Educ, Xian 710054, Peoples R China; [Zheng, Dan; Bai, Bo] Changan Univ, Sch Water & Environm, Xian 710054, Peoples R China; [Wang, Kai] Beijing Normal Univ, Coll Water Sci, Beijing 100875, Peoples R China; [Bai, Bo; Hu, Na; Wang, Honglun] Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810008, Peoples R China |
推荐引用方式 GB/T 7714 | Zheng, Dan,Wang, Kai,Bai, Bo,et al. Swelling and glyphosate-controlled release behavior of multi-responsive alginate-g-P(NIPAm-co-NDEAm)-based hydrogel[J]. 中国科学院西北生态环境资源研究院,2022,282. |
APA | Zheng, Dan,Wang, Kai,Bai, Bo,Hu, Na,&Wang, Honglun.(2022).Swelling and glyphosate-controlled release behavior of multi-responsive alginate-g-P(NIPAm-co-NDEAm)-based hydrogel.CARBOHYDRATE POLYMERS,282. |
MLA | Zheng, Dan,et al."Swelling and glyphosate-controlled release behavior of multi-responsive alginate-g-P(NIPAm-co-NDEAm)-based hydrogel".CARBOHYDRATE POLYMERS 282(2022). |
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