气候变化领域集成服务门户(CCPortal): Hyperacmosins K-M, three new polycyclic polyprenylated acylphloroglucinols from Hypericum acmosepalum

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DOI	10.1039/d1ra03533a
	Hyperacmosins K-M, three new polycyclic polyprenylated acylphloroglucinols from Hypericum acmosepalum
	Sun, Mingxia; Wang, Xue; Zhu, Tingting; Suo, Xinyue; Wang, Jiajia; Ji, Tengfei; Liu, Bo
通讯作者	Ji, TF (通讯作者)，Chinese Acad Med Sci & Peking Union Med Coll, Inst Mat Med, State Key Lab Bioact Subst & Funct Nat Med, Beijing 100050, Peoples R China. ; Ji, TF (通讯作者)，Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810008, Peoples R China. ; Liu, B (通讯作者)，Shenyang Med Coll, Sch Pharm, Shenyang 110034, Peoples R China.
发表日期	2021
EISSN	2046-2069
起始页码	21029
结束页码	21035
卷号	11 期号:34
英文摘要	Hyperacmosins K-M (1-3), three new polycyclic polyprenylated acylphloroglucinol (PPAPs) derivatives, were isolated from the air-dried aerial parts of Hypericum asmosepalum. Compounds 1 and 2 both possessed a rare 5,5-spiroketal subunit with the loss of C-2 ' carbonyl in the phloroglucinal ring, while compound 3 featured an unusual 1,2-seco-bicyclo[3.3.1] PPAP skeleton. Their structures were confirmed by NMR, HRESIMS, and CD spectra. The plausible biogenetic pathways of 1-3 were proposed, which gave an insight for future biomimetic synthesis of the novel compounds.
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000664786000049
来源期刊	RSC ADVANCES
来源机构	中国科学院西北生态环境资源研究院
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/254363
作者单位	[Sun, Mingxia; Wang, Xue; Zhu, Tingting; Suo, Xinyue; Wang, Jiajia; Ji, Tengfei] Chinese Acad Med Sci & Peking Union Med Coll, Inst Mat Med, State Key Lab Bioact Subst & Funct Nat Med, Beijing 100050, Peoples R China; [Ji, Tengfei] Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810008, Peoples R China; [Liu, Bo] Shenyang Med Coll, Sch Pharm, Shenyang 110034, Peoples R China
推荐引用方式 GB/T 7714	Sun, Mingxia,Wang, Xue,Zhu, Tingting,et al. Hyperacmosins K-M, three new polycyclic polyprenylated acylphloroglucinols from Hypericum acmosepalum[J]. 中国科学院西北生态环境资源研究院,2021,11(34).
APA	Sun, Mingxia.,Wang, Xue.,Zhu, Tingting.,Suo, Xinyue.,Wang, Jiajia.,...&Liu, Bo.(2021).Hyperacmosins K-M, three new polycyclic polyprenylated acylphloroglucinols from Hypericum acmosepalum.RSC ADVANCES,11(34).
MLA	Sun, Mingxia,et al."Hyperacmosins K-M, three new polycyclic polyprenylated acylphloroglucinols from Hypericum acmosepalum".RSC ADVANCES 11.34(2021).