气候变化领域集成服务门户(CCPortal): Metal-free visible-light-induced aerobic oxidation of alpha-diazoesters leading to alpha-ketoesters in air

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DOI	10.1039/d0qo01587c
	Metal-free visible-light-induced aerobic oxidation of alpha-diazoesters leading to alpha-ketoesters in air
	Liu, Ruisheng; Liu, Qishun; Meng, Haoran; Ding, Hongyu; Hao, Jindong; Ji, Zhongyin; Yue, Huilan; Wei, Wei
通讯作者	Wei, W (通讯作者)，Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China. ; Yue, HL (通讯作者)，Chinese Acad Sci, Northwest Inst Plateau Biol, Qinghai Prov Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China. ; Yue, HL (通讯作者)，Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China.
发表日期	2021
ISSN	2052-4129
起始页码	1970
结束页码	1975
卷号	8 期号:9
英文摘要	A metal-free and visible-light-promoted strategy has been achieved for the construction of alpha-ketoesters via aerobic oxidation of alpha-diazoesters with dioxygen in air at room temperature. Using cheap, readily available Eosin Y as the photocatalyst and O-2(air) as the green oxidant, the present protocol offers a mild and efficient approach to a wide range of alpha-ketoesters in moderate to good yields. Preliminary mechanistic studies suggested that photo-excited singlet oxygen was involved in the present reaction system.
关键词	KETO-ESTERS SINGLET OXYGEN STEREOSELECTIVE-SYNTHESIS EFFICIENT SYNTHESIS CARBENE COMPLEXES DIAZO-COMPOUNDS BETA-KETO N-OXIDES ACIDS STRATEGY
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000646804500008
来源期刊	ORGANIC CHEMISTRY FRONTIERS
来源机构	中国科学院西北生态环境资源研究院
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/253834
作者单位	[Liu, Ruisheng; Liu, Qishun; Meng, Haoran; Ding, Hongyu; Hao, Jindong; Ji, Zhongyin; Wei, Wei] Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China; [Yue, Huilan] Chinese Acad Sci, Northwest Inst Plateau Biol, Qinghai Prov Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China; [Yue, Huilan] Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China
推荐引用方式 GB/T 7714	Liu, Ruisheng,Liu, Qishun,Meng, Haoran,et al. Metal-free visible-light-induced aerobic oxidation of alpha-diazoesters leading to alpha-ketoesters in air[J]. 中国科学院西北生态环境资源研究院,2021,8(9).
APA	Liu, Ruisheng.,Liu, Qishun.,Meng, Haoran.,Ding, Hongyu.,Hao, Jindong.,...&Wei, Wei.(2021).Metal-free visible-light-induced aerobic oxidation of alpha-diazoesters leading to alpha-ketoesters in air.ORGANIC CHEMISTRY FRONTIERS,8(9).
MLA	Liu, Ruisheng,et al."Metal-free visible-light-induced aerobic oxidation of alpha-diazoesters leading to alpha-ketoesters in air".ORGANIC CHEMISTRY FRONTIERS 8.9(2021).