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DOI	10.5194/acp-20-5945-2020
	Insights into atmospheric oxidation processes by performing factor analyses on subranges of mass spectra
	Zhang Y.; Peräkylä O.; Yan C.; Heikkinen L.; Äijälä M.; Daellenbach K.R.; Zha Q.; Riva M.; Garmash O.; Junninen H.; Paatero P.; Worsnop D.; Ehn M.
发表日期	2020
ISSN	1680-7316
起始页码	5945
结束页码	5961
卷号	20 期号:10
英文摘要	Our understanding of atmospheric oxidation chemistry has improved significantly in recent years, greatly facilitated by developments in mass spectrometry. The generated mass spectra typically contain vast amounts of information on atmospheric sources and processes, but the identification and quantification of these is hampered by the wealth of data to analyze. The implementation of factor analysis techniques have greatly facilitated this analysis, yet many atmospheric processes still remain poorly understood. Here, we present new insights into highly oxygenated products from monoterpene oxidation, measured by chemical ionization mass spectrometry, at a boreal forest site in Finland in autumn 2016. Our primary focus was on the formation of accretion products, i.e., dimers. We identified the formation of daytime dimers, with a diurnal peak at noontime, despite high nitric oxide (NO) concentrations typically expected to inhibit dimer formation. These dimers may play an important role in new particle formation events that are often observed in the forest. In addition, dimers identified as combined products of NO3 and O3 oxidation of monoterpenes were also found to be a large source of low-volatility vapors at night. This highlights the complexity of atmospheric oxidation chemistry and the need for future laboratory studies on multi-oxidant systems. These two processes could not have been separated without the new analysis approach deployed in our study, where we applied binned positive matrix factorization (binPMF) on subranges of the mass spectra rather than the traditional approach where the entire mass spectrum is included for PMF analysis. In addition to the main findings listed above, several other benefits compared to traditional methods were found. © Author(s) 2020.
语种	英语
scopus关键词	atmospheric chemistry; boreal forest; factor analysis; ionization; mass spectrometry; oxidation; oxygenation; Finland
来源期刊	ATMOSPHERIC CHEMISTRY AND PHYSICS
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/247769
作者单位	Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland; Univ. Lyon, Université Claude Bernard Lyon 1, CNRS, IRCELYON, Villeurbanne, 69626, France; Institute of Physics, University of Tartu, Tartu, 50090, Estonia; Aerodyne Research, Inc., Billerica, MA 01821, United States
推荐引用方式 GB/T 7714	Zhang Y.,Peräkylä O.,Yan C.,et al. Insights into atmospheric oxidation processes by performing factor analyses on subranges of mass spectra[J],2020,20(10).
APA	Zhang Y..,Peräkylä O..,Yan C..,Heikkinen L..,Äijälä M..,...&Ehn M..(2020).Insights into atmospheric oxidation processes by performing factor analyses on subranges of mass spectra.ATMOSPHERIC CHEMISTRY AND PHYSICS,20(10).
MLA	Zhang Y.,et al."Insights into atmospheric oxidation processes by performing factor analyses on subranges of mass spectra".ATMOSPHERIC CHEMISTRY AND PHYSICS 20.10(2020).