气候变化领域集成服务门户(CCPortal): Reformulating the bromine alpha factor and equivalent effective stratospheric chlorine (EESC): Evolution of ozone destruction rates of bromine and chlorine in future climate scenarios

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DOI	10.5194/acp-20-9459-2020
	Reformulating the bromine alpha factor and equivalent effective stratospheric chlorine (EESC): Evolution of ozone destruction rates of bromine and chlorine in future climate scenarios
	Eric Klobas J.; Weisenstein D.K.; Salawitch R.J.; Wilmouth D.M.
发表日期	2020
ISSN	1680-7316
起始页码	9459
结束页码	9471
卷号	20 期号:15
英文摘要	Future trajectories of the stratospheric trace gas background will alter the rates of bromine- and chlorine-mediated catalytic ozone destruction via changes in the partitioning of inorganic halogen reservoirs and the underlying temperature structure of the stratosphere. The current formulation of the bromine alpha factor, the ozone-destroying power of stratospheric bromine atoms relative to stratospheric chlorine atoms, is invariant with the climate state. Here, we refactor the bromine alpha factor, introducing normalization to a benchmark chemistry-climate state, and formulate Equivalent Effective Stratospheric Benchmark-normalized Chlorine (EESBnC) to reflect changes in the rates of both bromine- and chlorine-mediated ozone loss catalysis with time. We show that the ozone-processing power of the extrapolar stratosphere is significantly perturbed by future climate assumptions. Furthermore, we show that our EESBnC-based estimate of the extrapolar ozone recovery date is in closer agreement with extrapolar ozone recovery dates predicted using more sophisticated 3-D chemistry-climate models than predictions made using equivalent effective stratospheric chlorine (EESC). © Author(s) 2020. This work is distributed under the Creative Commons Attribution 4.0 License.
语种	英语
来源期刊	ATMOSPHERIC CHEMISTRY AND PHYSICS
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/247590
作者单位	Harvard John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, MA, United States; Department of Atmospheric and Oceanic Science, Department of Chemistry and Biochemistry, Earth System Science Interdisciplinary Center, University of Maryland, College Park, MD, United States
推荐引用方式 GB/T 7714	Eric Klobas J.,Weisenstein D.K.,Salawitch R.J.,et al. Reformulating the bromine alpha factor and equivalent effective stratospheric chlorine (EESC): Evolution of ozone destruction rates of bromine and chlorine in future climate scenarios[J],2020,20(15).
APA	Eric Klobas J.,Weisenstein D.K.,Salawitch R.J.,&Wilmouth D.M..(2020).Reformulating the bromine alpha factor and equivalent effective stratospheric chlorine (EESC): Evolution of ozone destruction rates of bromine and chlorine in future climate scenarios.ATMOSPHERIC CHEMISTRY AND PHYSICS,20(15).
MLA	Eric Klobas J.,et al."Reformulating the bromine alpha factor and equivalent effective stratospheric chlorine (EESC): Evolution of ozone destruction rates of bromine and chlorine in future climate scenarios".ATMOSPHERIC CHEMISTRY AND PHYSICS 20.15(2020).