气候变化领域集成服务门户(CCPortal): Importance of secondary organic aerosol formation of iα/i-pinene, limonene, and im/i-cresol comparing day- And nighttime radical chemistry

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DOI	10.5194/acp-21-8479-2021
	Importance of secondary organic aerosol formation of iα/i-pinene, limonene, and im/i-cresol comparing day- And nighttime radical chemistry
	Mutzel A.; Zhang Y.; Böge O.; Rodigast M.; Kolodziejczyk A.; Wang X.; Herrmann H.
发表日期	2021
ISSN	1680-7316
起始页码	8479
结束页码	8498
卷号	21 期号:11
英文摘要	The oxidation of biogenic and anthropogenic compounds leads to the formation of secondary organic aerosol mass (SOA). The present study aims to investigate span classCombining double low line"inline-formula"iα/i/span-pinene, limonene, and span classCombining double low line"inline-formula"im/i/span-cresol with regards to their SOA formation potential dependent on relative humidity (RH) under night- (NOspan classCombining double low line"inline-formula"3/span radicals) and daytime conditions (OH radicals) and the resulting chemical composition. It was found that SOA formation potential of limonene with NOspan classCombining double low line"inline-formula"3/span under dry conditions significantly exceeds that of the OH-radical reaction, with SOA yields of 15-30 % and 10-21 %, respectively. Additionally, the nocturnal SOA yield was found to be very sensitive towards RH, yielding more SOA under dry conditions. In contrast, the SOA formation potential of span classCombining double low line"inline-formula"iα/i/span-pinene with NOspan classCombining double low line"inline-formula"3/span slightly exceeds that of the OH-radical reaction, independent from RH. On average, span classCombining double low line"inline-formula"iα/i/span-pinene yielded SOA with about 6-7 % from NOspan classCombining double low line"inline-formula"3/span radicals and 3-4 % from OH-radical reaction. Surprisingly, unexpectedly high SOA yields were found for span classCombining double low line"inline-formula"im/i/span-cresol oxidation with OH radicals (3-9 %), with the highest yield under elevated RH (9 %), which is most likely attributable to a higher fraction of 3-methyl-6-nitro-catechol (MNC). While span classCombining double low line"inline-formula"iα/i/span-pinene and span classCombining double low line"inline-formula"im/i/span-cresol SOA was found to be mainly composed of water-soluble compounds, 50-68 % of nocturnal SOA and 22-39 % of daytime limonene SOA are water-insoluble. The fraction of SOA-bound peroxides which originated from span classCombining double low line"inline-formula"iα/i/span-pinene varied between 2 and 80 % as a function of RH./p pFurthermore, SOA from span classCombining double low line"inline-formula"iα/i/span-pinene revealed pinonic acid as the most important particle-phase constituent under day- and nighttime conditions with a fraction of 1-4 %. Other compounds detected are norpinonic acid (0.05-1.1 % mass fraction), terpenylic acid (0.1-1.1 % mass fraction), pinic acid (0.1-1.8 % mass fraction), and 3-methyl-1,2,3-tricarboxylic acid (0.05-0.5 % mass fraction). All marker compounds showed higher fractions under dry conditions when formed during daytime and showed almost no RH effect when formed during night./p © 2021 Copernicus GmbH. All rights reserved.
语种	英语
scopus关键词	aerosol; anthropogenic source; atmospheric chemistry; chemical compound; concentration (composition); hydroxyl radical; relative humidity
来源期刊	ATMOSPHERIC CHEMISTRY AND PHYSICS
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/246838
作者单位	Leibniz Institute for Tropospheric Research (TROPOS), Atmospheric Chemistry Department (ACD), Permoserstr. 15, Leipzig, 04318, Germany; State Key Lab. of Organ. Geochem. and Guangdong Key Lab. of Environ. Protect. and Rsrc. Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, 510640, China; Institute of Physical Chemistry of the Polish Academy of Sciences, Kasprzaka 44/52, Warsaw, 01-224, Poland; Eurofins Institute Dr. Appelt Leipzig, Täubchenweg 28, Leipzig, 04318, Germany; Indulor Chemie GmbH and Co. KG Produktionsgesellschaft Bitterfeld, Bitterfeld-Wolfen, 06749, Germany
推荐引用方式 GB/T 7714	Mutzel A.,Zhang Y.,Böge O.,et al. Importance of secondary organic aerosol formation of iα/i-pinene, limonene, and im/i-cresol comparing day- And nighttime radical chemistry[J],2021,21(11).
APA	Mutzel A..,Zhang Y..,Böge O..,Rodigast M..,Kolodziejczyk A..,...&Herrmann H..(2021).Importance of secondary organic aerosol formation of iα/i-pinene, limonene, and im/i-cresol comparing day- And nighttime radical chemistry.ATMOSPHERIC CHEMISTRY AND PHYSICS,21(11).
MLA	Mutzel A.,et al."Importance of secondary organic aerosol formation of iα/i-pinene, limonene, and im/i-cresol comparing day- And nighttime radical chemistry".ATMOSPHERIC CHEMISTRY AND PHYSICS 21.11(2021).