气候变化领域集成服务门户(CCPortal): Visualizing gas molecules interacting with supported nanoparticulate catalysts at reaction conditions

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DOI	10.1126/science.1213194
	Visualizing gas molecules interacting with supported nanoparticulate catalysts at reaction conditions
	Yoshida H.; Kuwauchi Y.; Jinschek J.R.; Sun K.; Tanaka S.; Kohyama M.; Shimada S.; Haruta M.; Takeda S.
发表日期	2012
ISSN	0036-8075
起始页码	317
结束页码	319
卷号	335 期号:6066
英文摘要	Understanding how molecules can restructure the surfaces of heterogeneous catalysts under reaction conditions requires methods that can visualize atoms in real space and time. We applied a newly developed aberration-corrected environmental transmission electron microscopy to show that adsorbed carbon monoxide (CO) molecules caused the {100} facets of a gold nanoparticle to reconstruct during CO oxidation at room temperature. The CO molecules adsorbed at the on-top sites of gold atoms in the reconstructed surface, and the energetic favorability of this reconstructed structure was confirmed by ab initio calculations and image simulations. This atomic-scale visualizing method can be applied to help elucidate reaction mechanisms in heterogeneous catalysis.
英文关键词	carbon monoxide; gold nanoparticle; carbon monoxide; catalyst; heterogeneity; mathematical analysis; molecular analysis; numerical model; oxidation; oxide; particulate matter; reconstruction; temperature effect; transmission electron microscopy; visualization; article; atom; catalysis; gas; molecule; oxidation; priority journal; room temperature; transmission electron microscopy
语种	英语
来源期刊	Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/246108
作者单位	Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0047, Japan; Department of Physics, Graduate School of Science, Osaka University, 1-1 Machikaneyama, Toyonaka, Osaka 560-0043, Japan; FEI Company, 5651 GG Eindhoven, Netherlands; Research Institute for Ubiquitous Energy Devices, National Institute of Advanced Industrial Science and Technology (AIST), Midorigaoka, Ikeda, Osaka 563-8577, Japan; Department of Applied Chemistry, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1 Minami-osawa, Hachioji, Tokyo 192-0397, Japan
推荐引用方式 GB/T 7714	Yoshida H.,Kuwauchi Y.,Jinschek J.R.,et al. Visualizing gas molecules interacting with supported nanoparticulate catalysts at reaction conditions[J],2012,335(6066).
APA	Yoshida H..,Kuwauchi Y..,Jinschek J.R..,Sun K..,Tanaka S..,...&Takeda S..(2012).Visualizing gas molecules interacting with supported nanoparticulate catalysts at reaction conditions.Science,335(6066).
MLA	Yoshida H.,et al."Visualizing gas molecules interacting with supported nanoparticulate catalysts at reaction conditions".Science 335.6066(2012).