气候变化领域集成服务门户(CCPortal): Perovskites in catalysis and electrocatalysis

CCPortal

DOI	10.1126/science.aam7092
	Perovskites in catalysis and electrocatalysis
	Hwang J.; Rao R.R.; Giordano L.; Katayama Y.; Yu Y.; Shao-Horn Y.
发表日期	2017
ISSN	0036-8075
起始页码	751
结束页码	756
卷号	358 期号:6364
英文摘要	Catalysts for chemical and electrochemical reactions underpin many aspects of modern technology and industry, from energy storage and conversion to toxic emissions abatement to chemical and materials synthesis. This role necessitates the design of highly active, stable, yet earth-abundant heterogeneous catalysts. In this Review, we present the perovskite oxide family as a basis for developing such catalysts for (electro)chemical conversions spanning carbon, nitrogen, and oxygen chemistries. A framework for rationalizing activity trends and guiding perovskite oxide catalyst design is described, followed by illustrations of how a robust understanding of perovskite electronic structure provides fundamental insights into activity, stability, and mechanism in oxygen electrocatalysis. We conclude by outlining how these insights open experimental and computational opportunities to expand the compositional and chemical reaction space for next-generation perovskite catalysts. © 2017, American Association for the Advancement of Science. All rights reserved.
英文关键词	carbon; nitric oxide; nitrogen; nitrogen derivative; oxygen; perovskite; catalysis; catalyst; chemical reaction; electrochemical method; experimental study; oxygen; perovskite; toxic substance; artificial intelligence; atmospheric pressure; catalysis; catalyst; electrocatalysis; electrochemical analysis; energy transfer; machine learning; oxidation; oxygen enhancement ratio; priority journal; reduction (chemistry); Review; superconductivity; surface property
语种	英语
来源期刊	Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/244110
作者单位	Department of Materials Science and Engineering, Massachusetts Institute of Technology (MIT), Cambridge, MA 02139, United States; Department of Mechanical Engineering, MIT, Cambridge, MA 02139, United States; Department of Material Science, Università di Milano-Bicocca, Via Cozzi 55, Milano, 20136, Italy; Research, Laboratory of Electronics, MIT, Cambridge, MA 02139, United States; Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Kyoto, 615-8510, Japan
推荐引用方式 GB/T 7714	Hwang J.,Rao R.R.,Giordano L.,et al. Perovskites in catalysis and electrocatalysis[J],2017,358(6364).
APA	Hwang J.,Rao R.R.,Giordano L.,Katayama Y.,Yu Y.,&Shao-Horn Y..(2017).Perovskites in catalysis and electrocatalysis.Science,358(6364).
MLA	Hwang J.,et al."Perovskites in catalysis and electrocatalysis".Science 358.6364(2017).