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DOI | 10.1073/pnas.2109408118 |
Electrochemical borylation of carboxylic acids | |
Barton L.M.; Chen L.; Blackmond D.G.; Baran P.S. | |
发表日期 | 2021 |
ISSN | 0027-8424 |
卷号 | 118期号:34 |
英文摘要 | A simple electrochemically mediated method for the conversion of alkyl carboxylic acids to their borylated congeners is presented. This protocol features an undivided cell setup with inexpensive carbon-based electrodes and exhibits a broad substrate scope and scalability in both flow and batch reactors. The use of this method in challenging contexts is exemplified with a modular formal synthesis of jawsamycin, a natural product harboring five cyclopropane rings. © 2021 National Academy of Sciences. All rights reserved. |
英文关键词 | Electrochemistry; Organic synthesis; Total synthesis |
语种 | 英语 |
来源期刊 | Proceedings of the National Academy of Sciences of the United States of America |
文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/238420 |
作者单位 | Department of Chemistry, Scripps Research, San Diego, CA 92037, United States |
推荐引用方式 GB/T 7714 | Barton L.M.,Chen L.,Blackmond D.G.,et al. Electrochemical borylation of carboxylic acids[J],2021,118(34). |
APA | Barton L.M.,Chen L.,Blackmond D.G.,&Baran P.S..(2021).Electrochemical borylation of carboxylic acids.Proceedings of the National Academy of Sciences of the United States of America,118(34). |
MLA | Barton L.M.,et al."Electrochemical borylation of carboxylic acids".Proceedings of the National Academy of Sciences of the United States of America 118.34(2021). |
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