气候变化领域集成服务门户(CCPortal): Electrochemical borylation of carboxylic acids

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DOI	10.1073/pnas.2109408118
	Electrochemical borylation of carboxylic acids
	Barton L.M.; Chen L.; Blackmond D.G.; Baran P.S.
发表日期	2021
ISSN	0027-8424
卷号	118 期号:34
英文摘要	A simple electrochemically mediated method for the conversion of alkyl carboxylic acids to their borylated congeners is presented. This protocol features an undivided cell setup with inexpensive carbon-based electrodes and exhibits a broad substrate scope and scalability in both flow and batch reactors. The use of this method in challenging contexts is exemplified with a modular formal synthesis of jawsamycin, a natural product harboring five cyclopropane rings. © 2021 National Academy of Sciences. All rights reserved.
英文关键词	Electrochemistry; Organic synthesis; Total synthesis
语种	英语
来源期刊	Proceedings of the National Academy of Sciences of the United States of America
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/238420
作者单位	Department of Chemistry, Scripps Research, San Diego, CA 92037, United States
推荐引用方式 GB/T 7714	Barton L.M.,Chen L.,Blackmond D.G.,et al. Electrochemical borylation of carboxylic acids[J],2021,118(34).
APA	Barton L.M.,Chen L.,Blackmond D.G.,&Baran P.S..(2021).Electrochemical borylation of carboxylic acids.Proceedings of the National Academy of Sciences of the United States of America,118(34).
MLA	Barton L.M.,et al."Electrochemical borylation of carboxylic acids".Proceedings of the National Academy of Sciences of the United States of America 118.34(2021).