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DOI | https://doi.org/10.1594/PANGAEA.834595 |
Concentrations of perfluorinated carboxylic acids (PFCAs) and sulfonic acids (PFSAs) in liver samples of different marine mammals (1984-2009) | |
Rotander; Anna; Kärrman; Anna; van Bavel; Bert; Polder; Anuschka; Rigét; Frank F; Auðunsson; Guðjón Atli; Víkingsson; Gísli; Gabrielsen; Geir W; Bloch; Dorete; Dam; Maria | |
发布日期 | 2012-07-31 |
数据集类型 | dataset |
英文简介 | Temporal variations in concentrations of perfluorinated carboxylic acids (PFCAs) and sulfonic acids (PFSAs), including perfluorooctane sulfonate (PFOS) and perfluorooctanoate (PFOA) structural isomers, were examined in livers of pilot whale (Globicephala melas), ringed seal (Phoca hispida), minke whale (Balaenoptera acutorostrata), harbor porpoise (Phocoena phocoena), hooded seal (Cystophora cristata), Atlantic white-sided dolphin (Lagenorhynchus acutus) and in muscle tissue of fin whales (Balaenoptera physalus). The sampling spanned over 20 years (1984-2009) and covered a large geographical area of the North Atlantic and West Greenland. Liver and muscle samples were homogenized, extracted with acetonitrile, cleaned up using hexane and solid phase extraction (SPE), and analyzed by liquid chromatography with negative electrospray tandem mass spectrometry (LC-MS/MS). In general, the levels of the long-chained PFCAs (C9-C12) increased whereas the levels of PFOS remained steady over the studied period. The PFOS isomer pattern in pilot whale liver was relatively constant over the sampling years. However, in ringed seals there seemed to be a decrease in linear PFOS (L-PFOS) with time, going from 91% in 1984 to 83% in 2006. |
空间范围 | Median Latitude: 69.436784 * Median Longitude: -37.792238 * South-bound Latitude: 61.700000 * West-bound Longitude: -69.350000 * North-bound Latitude: 77.470000 * East-bound Longitude: -7.300000 |
时间范围 | 2001-02-18T00:00:00 - 2001-03-01T00:00:00 |
语种 | 英语 |
国家 | 国际 |
学科大类 | 气候变化 |
学科子类 | 气候变化 |
文献类型 | 数据集 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/215493 |
推荐引用方式 GB/T 7714 | Rotander,Anna,Kärrman,et al. Concentrations of perfluorinated carboxylic acids (PFCAs) and sulfonic acids (PFSAs) in liver samples of different marine mammals (1984-2009).2012-07-31.https://doi.org/10.1594/PANGAEA.834595. |
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