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DOI10.1016/j.earscirev.2021.103509
Fluids associated with carbonatitic magmatism: A critical review and implications for carbonatite magma ascent
Walter B.F.; Giebel R.J.; Steele-MacInnis M.; Marks M.A.W.; Kolb J.; Markl G.
发表日期2021
ISSN0012-8435
卷号215
英文摘要Carbonatites are formed from volatile-rich melts, commonly associated with a characteristic hydrothermal footprint. However, studies of their fluid inclusions are relatively scarce and heterogeneous in terms of detail and completeness of the data presented. Here, we review and discuss comprehensively the results of previous studies and derive a general model for the formation and properties of fluids associated with carbonatitic magmatism. Worldwide, four types of fluid inclusion occur in carbonatites: (type I/HS) vapour-poor H2O-NaCl fluids with up to 50 wt% salinity; (type II/HC) vapour-rich H2O-NaCl-CO2 fluids with <5 wt% salinity; (type III/DS) multi-component fluids with high salinity and without CO2; and (type IV/CDS) multi-component fluids with high salinity and high CO2. This global dataset suggests continuous fluid release from deep to shallow-level intrusions. Modelling of the liquidus surface indicates that carbonatite magmas generally exsolve a saline brine (type I/HS). This brine separates/evolves into a Na-K-sulfate-carbonate/bicarbonate-chloride brine with or without CO2 (types III/DS and IV/CDS), trapped together with low salinity CO2-rich fluids produced by immiscibility. Fluid immiscibility is related to rapid pressure release during fast, forceful and discontinuous magma ascent, which we envisage as a “pneumatic jackhammer” model for carbonatite ascent and emplacement. In this model, cyclic and progressive fluid flux via pressure build-up and subsequent catastrophic pressure release results in a self-sustaining crustal ascent of the buoyant, low-viscosity magma. This process allows for rapid and efficient magma ascent, in particular above the brittle-ductile transition zone, where pressures that prevailed during apatite crystallization have been estimated in numerous complexes. Moreover, this model provides an explanation for the apparent absence of shallow carbonatite magma chambers (in a classical sense) and identifies fenitization as a phenomenon induced by both fluids released during magma ascent and residual fluids. © 2021 Elsevier B.V.
英文关键词Carbonatite-derived fluids; Carbonatites; Fluid inclusions; High field-strength elements; Hydrothermal; Jackhammer process; Magmatic; Rapid magma ascent; Rare Earth elements
语种英语
scopus关键词carbon dioxide; carbonatite; crystallization; fluid inclusion; hydrothermal system; igneous geochemistry; igneous intrusion; immiscibility; magmatism
来源期刊EARTH-SCIENCE REVIEWS
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/209364
作者单位Karlsruhe Institute of Technology, Adenauerring 20b, Karlsruhe, 76131, Germany; Eberhard Karls University Tübingen, Wilhelmstr. 56, Tübingen, 72074, Germany; Technical University of Berlin, Ernst-Reuter-Platz 1, Berlin, 10587, Germany; University of the Free State, 250 Nelson-Mandela-Drive, Bloemfontein, 9300, South Africa; University of Alberta, 1-26 Earth Sciences Building, Edmonton, AB T6G2E3, Canada
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Walter B.F.,Giebel R.J.,Steele-MacInnis M.,et al. Fluids associated with carbonatitic magmatism: A critical review and implications for carbonatite magma ascent[J],2021,215.
APA Walter B.F.,Giebel R.J.,Steele-MacInnis M.,Marks M.A.W.,Kolb J.,&Markl G..(2021).Fluids associated with carbonatitic magmatism: A critical review and implications for carbonatite magma ascent.EARTH-SCIENCE REVIEWS,215.
MLA Walter B.F.,et al."Fluids associated with carbonatitic magmatism: A critical review and implications for carbonatite magma ascent".EARTH-SCIENCE REVIEWS 215(2021).
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