气候变化领域集成服务门户(CCPortal): Mantle sources and magma evolution in Europe's largest rare earth element belt (Gardar Province, SW Greenland): New insights from sulfur isotopes

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DOI	10.1016/j.epsl.2021.117034
	Mantle sources and magma evolution in Europe's largest rare earth element belt (Gardar Province, SW Greenland): New insights from sulfur isotopes
	Hutchison W.; Finch A.A.; Borst A.M.; Marks M.A.W.; Upton B.G.J.; Zerkle A.L.; Stüeken E.E.; Boyce A.J.
发表日期	2021
ISSN	0012821X
卷号	568
英文摘要	Alkaline igneous complexes are often rich in rare earth elements (REE) and other metals essential for modern technologies. Although a variety of magmatic and hydrothermal processes explain the occurrence of individual deposits, one common feature identified in almost all studies, is a REE-enriched parental melt sourced from the lithospheric mantle. Fundamental questions remain about the origin and importance of the mantle source in the genesis of REE-rich magmas. In particular, it is often unclear whether localized enrichments within an alkaline province reflect heterogeneity in the mantle source lithology (caused by prior subduction or plume activity) or variations in the degree of partial melting and differentiation of a largely homogeneous source. Sulfur isotopes offer a means of testing these hypotheses because they are unaffected by high temperature partial melting processes and can fingerprint different mantle sources. Although one must be careful to rule out subsequent isotope fractionation during magma ascent, degassing and crustal interactions. Here, we present new S concentration and isotope (δ34S) measurements, as well as a compilation of major and trace element data, for a suite of alkaline magmatic units and crustal lithologies from the Mesoproterozoic Gardar Province. Samples span all phases of Gardar magmatism (1330–1140 Ma) and include regional dykes, rift lavas and the alkaline complexes Motzfeldt and Ilímaussaq, which represent two of Europe's largest REE deposits. We show that the vast majority of our 115 samples have S contents >100 ppm and δ34S of −1 to 5‰. Only 8 samples (with low S contents, <100 ppm) show evidence for crustal interactions, implying that the vast majority of Gardar melts preserve the S isotopic signature of their magma source. Importantly, samples from across the Gardar Province have δ34S above the canonical mantle range (≤−1.4‰) and therefore require recycled surface S in their mantle source. Elevated δ34S values are explained by a period of Andean-style subduction and mantle metasomatism which took place ∼500 Ma before rift onset and are also supported by trace elements signatures (e.g. Ba/La) which match modern subduction zones. Comparing the various generations of Gardar magmas, we find that δ34S values, large ion lithophile elements (K, Ba, P) and selective incompatible elements (Nb and light REE) are particularly enriched in the Late Gardar dykes, alkaline complexes and clusters of silica-undersaturated dykes spatially associated with the alkaline complexes. These data indicate that subduction-related metasomatism of the Gardar mantle was spatially heterogeneous, and that alkaline complexes are sourced from localized mantle domains highly enriched in 34S, REE, alkalis and volatiles (particularly, F). Since alkalis and volatiles play an essential role in driving extreme differentiation of alkaline melts and fluids, we suggest the co-location of these species plus incompatible metals at high concentrations in the lithospheric mantle is a critical first-step in the genesis of a world-class alkaline REE deposit. S isotopes are powerful tools for identifying enriched mantle domains and the sources of mineralized alkaline igneous bodies. © 2021 The Author(s)
关键词	geochemistry magmatism REE rift sulfur volatiles
英文关键词	Deposits; Exploratory geochemistry; Isotopes; Lithology; Melting; Rare earths; Sulfur; Trace elements; Alkalines; Crustals; Lithospheric mantle; Localised; Magmatisms; Mantle source; Rare-earths; Rift; Sulfur isotope; Volatile; Rare earth elements; concentration (composition); enrichment; igneous geochemistry; lithospheric structure; magmatism; mantle source; mineralization; ore deposit; partial melting; rare earth element; source rock; sulfur; sulfur isotope; volatile element; Arctic; Gardar; Greenland
语种	英语
来源期刊	Earth and Planetary Science Letters
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/203142
作者单位	School of Earth and Environmental Sciences, University of St AndrewsKY16 9AL, United Kingdom; Mathematisch-Naturwissenschaftliche Fakultät, FB Geowissenschaften, Universität Tübingen, Wilhelmstrasse 56, Tübingen, 72074, Germany; School of GeoSciences, University of Edinburgh, Edinburgh, EH9 3JW, United Kingdom; Scottish Universities Environmental Research Centre, Rankine Avenue, East Kilbride, G75 0QF, United Kingdom
推荐引用方式 GB/T 7714	Hutchison W.,Finch A.A.,Borst A.M.,et al. Mantle sources and magma evolution in Europe's largest rare earth element belt (Gardar Province, SW Greenland): New insights from sulfur isotopes[J],2021,568.
APA	Hutchison W..,Finch A.A..,Borst A.M..,Marks M.A.W..,Upton B.G.J..,...&Boyce A.J..(2021).Mantle sources and magma evolution in Europe's largest rare earth element belt (Gardar Province, SW Greenland): New insights from sulfur isotopes.Earth and Planetary Science Letters,568.
MLA	Hutchison W.,et al."Mantle sources and magma evolution in Europe's largest rare earth element belt (Gardar Province, SW Greenland): New insights from sulfur isotopes".Earth and Planetary Science Letters 568(2021).