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| DOI | 10.1016/j.epsl.2021.116952 |
| Triple oxygen and clumped isotopes in modern soil carbonate along an aridity gradient in the Serengeti, Tanzania | |
| Beverly E.J.; Levin N.E.; Passey B.H.; Aron P.G.; Yarian D.A.; Page M.; Pelletier E.M. | |
| 发表日期 | 2021 |
| ISSN | 0012821X |
| 卷号 | 567 |
| 英文摘要 | The isotopic composition of paleosol carbonates is used extensively to reconstruct past vegetation, climate, and altimetry, but poor constraints on soil evaporation and temperature have limited the utility of oxygen isotopes in the studies. Recent advances in carbonate clumped isotope thermometry (TΔ47) allow for independent controls on temperature, but the influence of evaporation remains unresolved. However, the sensitivity of 18O-17O-16O distributions to kinetic fractionation makes it possible to use triple oxygen isotopes (Δ′17O) to track evaporation in water. Recent work shows the sensitivity of Δ′17O to evaporation in lakes and lacustrine carbonates, but little is known about variation of Δ′17O in soil carbonates and their potential to track evaporation. For this study, we sampled soils across an aridity gradient in the Serengeti, Tanzania to evaluate how soil carbonate Δ′17O tracks soil water evaporation. Modern soil carbonates were collected from 11 sites across a transect of the Serengeti Ecosystem where mean annual precipitation and aridity index range from 499 to 846 mm yr−1 and 0.33 to 0.55, respectively. δ13C values range from −2.7 to 1.8‰ and reflect C4 dominated grasslands, whereas δ18O values of soil carbonates vary by ∼8‰ along a gradient in aridity. TΔ47 from these soil carbonates average 23 °C (1σ± 4 °C), which does not vary significantly across sites or with depth, likely due to minimal annual variation in temperature at the equator. Using these temperatures for each carbonate, reconstructed δ18O values of soil water are up to 6‰ higher than δ18O values of local precipitation and springs, indicating considerable soil water evaporation. The Δ′17O values of these soil carbonates range from −162 to −106 per meg and decrease as both aridity and δ18O values increase. Our results support the hypothesis that soil water evaporation drives the variance in δ18O and Δ′17O of soil carbonate in arid climates, demonstrating the potential for soil carbonate Δ′17O to track paleoaridity and constrain interpretations of paleosol carbonate δ18O records. © 2021 Elsevier B.V. |
| 关键词 | Africaclumped isotopesevaporationpedogenic carbonatesoil temperaturetriple oxygen isotopes |
| 英文关键词 | Budget control; Carbonates; Carbonation; Evaporation; Oxygen; Sensitivity analysis; Soil moisture; Africa; Clumped isotopes; Isotopic composition; Palaeosols; Pedogenic carbonates; Soil evaporations; Soil temperature; Soil water evaporation; Tanzania; Triple oxygen isotopes; Isotopes; aridity; carbonate; evaporation; isotopic composition; oxygen isotope; paleosalinity; paleosol; soil temperature; soil water; Serengeti; Tanzania |
| 语种 | 英语 |
| 来源期刊 | Earth and Planetary Science Letters
 |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/203034 |
| 作者单位 | University of Houston, Earth and Atmospheric Sciences, 3507 Cullen Blvd, Room 214, Houston, TX 77204, United States; University of Michigan, Department of Earth & Environmental Sciences, 1100 North University Ave, Ann Arbor, MI 48109, United States |
| 推荐引用方式 GB/T 7714 | Beverly E.J.,Levin N.E.,Passey B.H.,et al. Triple oxygen and clumped isotopes in modern soil carbonate along an aridity gradient in the Serengeti, Tanzania[J],2021,567. |
| APA | Beverly E.J..,Levin N.E..,Passey B.H..,Aron P.G..,Yarian D.A..,...&Pelletier E.M..(2021).Triple oxygen and clumped isotopes in modern soil carbonate along an aridity gradient in the Serengeti, Tanzania.Earth and Planetary Science Letters,567. |
| MLA | Beverly E.J.,et al."Triple oxygen and clumped isotopes in modern soil carbonate along an aridity gradient in the Serengeti, Tanzania".Earth and Planetary Science Letters 567(2021). |
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