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DOI	10.1016/j.epsl.2020.116166
	Behaviour of chromium and chromium isotopes during estuarine mixing in the Beaulieu Estuary, UK
	Goring-Harford H.J.; Klar J.K.; Donald H.K.; Pearce C.R.; Connelly D.P.; James R.H.
发表日期	2020
ISSN	0012821X
卷号	536
英文摘要	Rivers are the principal source of chromium (Cr) to seawater and the Cr isotopic signatures of ancient marine sediments are widely considered to provide a record of the presence or absence of oxidative weathering processes on land. This assumes, however, that the δ53Cr value of river water is faithfully transferred to the oceans and is not modified in the estuarine mixing zone. To test this assumption we have determined the concentration and δ53Cr values of inorganic Cr (Cr(III) + Cr(VI)), and also Cr speciation for water samples collected within the estuarine mixing zone of the Beaulieu River, UK. The δ53Cr values of dissolved inorganic Cr ranged from −0.59 to 1.68‰, Cr(VI) concentrations from 0.39 to 1.83 nmol kg−1 and Cr(III) concentrations from 0.11 to 3.21 nmol kg−1. Both Cr(VI) concentrations and δ53Cr values increased linearly as a function of salinity, while Cr(III) concentrations decreased linearly with salinity. Thus δ53Cr, Cr(III) and Cr(VI) all showed conservative behaviour in the estuarine mixing zone, and the δ53Cr signature of Beaulieu River water was modified only by mixing between the river and seawater endmembers. The calculated average δ53Cr value of the river water endmember (−0.39 ± 0.08‰) was, however, lower than the range that has been observed in other rivers, which we attribute to input of organically-bound Cr(III) released by anoxic weathering processes. This is supported by the fact that Cr recovered by UV irradiation was found to have low δ53Cr values (−0.11 to −0.75‰). While input of Cr from anoxic weathering processes is unlikely to be an important source of Cr to the oceans today, this suggests that processes other than oxidative weathering may have an influence on the δ53Cr values of estuarine and coastal waters on the local scale. The δ53Cr value of the coastal seawater endmember (1.6 ± 0.4‰) was also higher than the range observed in the deep open ocean, due to in situ biogeochemical cycling of Cr. These factors need to be considered in the interpretation of marine sedimentary δ53Cr records. © 2020 Elsevier B.V.
关键词	anoxic weathering chromium cycling chromium isotopes chromium speciation estuarine mixing
英文关键词	Estuaries; Irradiation; Isotopes; Mixing; Radioactive tracers; Rivers; Seawater; Submarine geology; Weathering; Biogeochemical cycling; Chromium speciation; Coastal seawater; Coastal waters; Isotopic signatures; Marine sediments; Oxidative weathering; Weathering process; Chromium compounds
语种	英语
来源期刊	Earth and Planetary Science Letters
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/202612
作者单位	School of Ocean and Earth Science, National Oceanography Centre, University of Southampton Waterfront Campus, Southampton, SO14 3ZH, United Kingdom; Université de Perpignan Via Domitia, Centre de Formation et de Recherche sur les Environnements Méditerranéens (CEFREM), UMR 5110, 52 Avenue Paul Alduy, Perpignan Cedex, F-66860, France; CNRS, CEFREM, UMR 5110, 52 Avenue Paul Alduy, Perpignan Cedex, F-66860, France; Marine Geoscience, National Oceanography Centre, University of Southampton Waterfront Campus, Southampton, SO14 3HZ, United Kingdom
推荐引用方式 GB/T 7714	Goring-Harford H.J.,Klar J.K.,Donald H.K.,et al. Behaviour of chromium and chromium isotopes during estuarine mixing in the Beaulieu Estuary, UK[J],2020,536.
APA	Goring-Harford H.J.,Klar J.K.,Donald H.K.,Pearce C.R.,Connelly D.P.,&James R.H..(2020).Behaviour of chromium and chromium isotopes during estuarine mixing in the Beaulieu Estuary, UK.Earth and Planetary Science Letters,536.
MLA	Goring-Harford H.J.,et al."Behaviour of chromium and chromium isotopes during estuarine mixing in the Beaulieu Estuary, UK".Earth and Planetary Science Letters 536(2020).