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Comparison of Thermal and Non-Thermal Protocols for Analysis of Isoprene Secondary Organic Aerosol (SOA) Generated under Conditions of Low Nitrogen Oxides (NOx)
项目编号2001027
Avram Gold (Principal Investigator)
项目主持机构University of North Carolina at Chapel Hill
开始日期2020-02-15
结束日期2023-01-31
英文摘要This project is focused on laboratory studies of the formation of secondary organic aerosol (SOA) in the atmosphere derived from the presence of isoprene. Isoprene is a compound produced and emitted by many species of trees and other plant materials. Experiments will be conducted in a laboratory chamber to investigate the formation of SOA and assess the possible presence of artifacts related to the use of certain experimental methods.

This study includes an in-depth, quantitative, molecular-level investigation of isoprene-SOA composition and aging. The objectives of the research are to: (1) synthesize standards to investigate artifact formation and to identify labile components degraded during conventional thermal GC-ESI/MS analysis of isoprene SOA formed under low-nitrogen oxide (NOx) conditions; (2) optimize hydrophilic interaction liquid chromatography (HILIC) protocols for separation of synthetic targets and SOA extracts; and (3) conduct an analysis of the SOA particles and identification of analytical artifacts/decomposition products by comparison of results from HILIC and GC/EI-MS protocols.

This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.
学科分类08 - 地球科学;0805 - 大气科学
资助机构US-NSF
项目经费596470
项目类型Standard Grant
国家US
语种英语
文献类型项目
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/191296
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Avram Gold .Comparison of Thermal and Non-Thermal Protocols for Analysis of Isoprene Secondary Organic Aerosol (SOA) Generated under Conditions of Low Nitrogen Oxides (NOx).2020.
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