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DOI	10.1039/d0ee01860k
	Photocatalytic and electrocatalytic transformations of C1 molecules involving C-C coupling
	Xie S.; Ma W.; Wu X.; Zhang H.; Zhang Q.; Wang Y.; Wang Y.
发表日期	2021
ISSN	17545692
起始页码	37
结束页码	89
卷号	14 期号:1
英文摘要	Selective transformation of one-carbon (C1) molecules, which are abundant or easily available and inexpensive carbon feedstocks, into value-added multi-carbon (C2+) compounds is a very attractive but highly challenging research target. Photocatalysis and electrocatalysis have offered great opportunities for the activation and controllable C-C coupling of C1 molecules under mild and environmentally benign conditions. This article provides a critical review on recent advances in photocatalytic and electrocatalytic conversions of major C1 molecules, including CO, CO2, CH4, CH3OH and HCHO, into C2+ compounds, such as C2H4, C3H6, ethanol and ethylene glycol, which play essential roles in the current chemical or energy industry. Besides the photocatalysts and electrocatalysts reported for these conversions, the structure-performance relationships and the key factors that control the activity and product selectivity are analysed to provide insights into the rational design of more efficient catalysts for the synthesis of C2+ compounds from C1 feedstocks. The active species, reaction intermediates and reaction or catalyst-functioning mechanism are discussed to deepen the understanding of the chemistry for the activation and selective C-C coupling of C1 molecules in the presence of solar energy or electrical energy. © The Royal Society of Chemistry.
英文关键词	Catalysis; Catalyst selectivity; Chemical activation; Electrocatalysis; Electrocatalysts; Ethylene; Ethylene glycol; Feedstocks; Photocatalysts; Product design; Reaction intermediates; Solar energy; Carbon feedstock; Efficient catalysts; Electrical energy; Electrocatalytic; Environmentally benign; Product selectivities; Selective transformation; Structure performance; Molecules; catalysis; electrokinesis; experimental study; molecular analysis; photolysis; research work; transformation
语种	英语
来源期刊	Energy & Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/190803
作者单位	State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China; State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Shanghai Research Institute of Petrochemical Technology, Sinopec Corp., Shanghai, 201208, China
推荐引用方式 GB/T 7714	Xie S.,Ma W.,Wu X.,et al. Photocatalytic and electrocatalytic transformations of C1 molecules involving C-C coupling[J],2021,14(1).
APA	Xie S..,Ma W..,Wu X..,Zhang H..,Zhang Q..,...&Wang Y..(2021).Photocatalytic and electrocatalytic transformations of C1 molecules involving C-C coupling.Energy & Environmental Science,14(1).
MLA	Xie S.,et al."Photocatalytic and electrocatalytic transformations of C1 molecules involving C-C coupling".Energy & Environmental Science 14.1(2021).