气候变化领域集成服务门户(CCPortal): Polyoxometalates (POMs): From electroactive clusters to energy materials

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DOI	10.1039/d0ee03407j
	Polyoxometalates (POMs): From electroactive clusters to energy materials
	Horn M.R.; Singh A.; Alomari S.; Goberna-Ferrón S.; Benages-Vilau R.; Chodankar N.; Motta N.; Ostrikov K.; Macleod J.; Sonar P.; Gomez-Romero P.; Dubal D.
发表日期	2021
ISSN	17545692
起始页码	1652
结束页码	1700
卷号	14 期号:4
英文摘要	Polyoxometalates (POMs) represent a class of nanomaterials, which hold enormous promise for a range of energy-related applications. Their promise is owing to their "special"structure that gives POMs a truly unique ability to control redox reactions in energy conversion and storage. One such amazing capability is their large number of redox active sites that arises from the complex three-dimensional cluster of metal-oxide ions linked together by oxygen atoms. Here, a critical review on how POMs emerged from being molecular clusters for fundamental studies, to next-generation materials for energy applications is provided. We highlight how exploiting the versatility and activity of these molecules can lead to improved performance in energy devices such as supercapacitors and batteries, and in energy catalyst applications. The potential of POMs across numerous fields is systematically outlined by investigating structure-property-performance relationships and the determinant factors for energy systems. Finally, the challenges and opportunities for this class of materials with respect to addressing our pressing energy-related concerns are identified. This journal is © The Royal Society of Chemistry.
英文关键词	Energy conversion; Metals; Redox reactions; Determinant factors; Energy applications; Energy conversion and storages; Fundamental studies; Molecular clusters; Redox-active sites; Structure property; Three-dimensional clusters; Polyoxometalates; chemical compound; electrochemical method; energy
语种	英语
来源期刊	Energy & Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/190728
作者单位	School of Chemistry and Physics, Queensland University of Technology (QUT), 2 George Street, Brisbane, QLD 4000, Australia; Catalan Institute of Nanoscience and Nanotechnology, ICN2 (CSIC-BIST) Campus UAB, Bellaterra Barcelona, E-08193, Spain; Department of Energy and Materials Engineering, Dongguk University-Seoul, Seoul, 04620, South Korea; Centre for Materials Science, Queensland University of Technology (QUT), 2 George Street, Brisbane, QLD 4000, Australia; Consejo Superior de Investigaciones Científicas (CSIC), Spain
推荐引用方式 GB/T 7714	Horn M.R.,Singh A.,Alomari S.,et al. Polyoxometalates (POMs): From electroactive clusters to energy materials[J],2021,14(4).
APA	Horn M.R..,Singh A..,Alomari S..,Goberna-Ferrón S..,Benages-Vilau R..,...&Dubal D..(2021).Polyoxometalates (POMs): From electroactive clusters to energy materials.Energy & Environmental Science,14(4).
MLA	Horn M.R.,et al."Polyoxometalates (POMs): From electroactive clusters to energy materials".Energy & Environmental Science 14.4(2021).