气候变化领域集成服务门户(CCPortal): Transition metal-based bimetallic MOFs and MOF-derived catalysts for electrochemical oxygen evolution reaction

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DOI	10.1039/d0ee03697h
	Transition metal-based bimetallic MOFs and MOF-derived catalysts for electrochemical oxygen evolution reaction
	Li S.; Gao Y.; Li N.; Ge L.; Bu X.; Feng P.
发表日期	2021
ISSN	17545692
起始页码	1897
结束页码	1927
卷号	14 期号:4
英文摘要	The oxygen evolution reaction (OER) is a critical electrochemical reaction in water splitting and rechargeable metal-air batteries. It plays a pivotal role in achieving high-efficiency clean-energy production and energy storage in these devices. Transition metal-based bimetallic MOFs (TMB MOFs) with two different metal ions possess specific synergistic effects, which could exhibit OER performance and stability superior to those of the corresponding monometallic MOFs for water oxidation. Benefiting from the diversity of chemical composition and structural type, TMB MOFs can also serve as precursors and templates to obtain alloy-particle-decorated carbon materials with high surface area, or metal compounds such as bimetallic sulfides, phosphides, and hydroxides with atomic-level mixing of heterometallic elements. These materials with high-density active sites exhibit much improved catalytic activity in the water oxidation reaction. This article aims to review the recent progress with TMB MOFs and their derivatives in relation to applications as electrocatalysts in OER, including analysis of the mechanism of the OER process with the assistance of DFT calculations and in situ or operando techniques. This journal is © The Royal Society of Chemistry.
英文关键词	Catalyst activity; Catalytic oxidation; Electrocatalysts; Energy storage; Metal ions; Metal-air batteries; Oxygen; Phosphorus compounds; Sulfur compounds; Transition metal compounds; Transition metals; Chemical compositions; Electrochemical oxygen; Electrochemical reactions; High surface area; High-efficiency; Oxygen evolution reaction (oer); Synergistic effect; Water oxidation; Oxygen evolution reaction; catalyst; chemical reaction; electrochemical method; oxygen; transition element
语种	英语
来源期刊	Energy & Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/190723
作者单位	State Key Laboratory of Heavy Oil Processing, College of New Energy and Materials, China University of Petroleum Beijing, No. 18 Fuxue Rd., Beijing, 102249, China; Department of Chemistry, University of California, Riverside, CA 92521, United States; Department of Chemistry and Biochemistry, California State University, Long Beach, Long Beach, CA 90840, United States
推荐引用方式 GB/T 7714	Li S.,Gao Y.,Li N.,et al. Transition metal-based bimetallic MOFs and MOF-derived catalysts for electrochemical oxygen evolution reaction[J],2021,14(4).
APA	Li S.,Gao Y.,Li N.,Ge L.,Bu X.,&Feng P..(2021).Transition metal-based bimetallic MOFs and MOF-derived catalysts for electrochemical oxygen evolution reaction.Energy & Environmental Science,14(4).
MLA	Li S.,et al."Transition metal-based bimetallic MOFs and MOF-derived catalysts for electrochemical oxygen evolution reaction".Energy & Environmental Science 14.4(2021).