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DOI10.1039/c6ee02770a
A new approach for recycling waste rubber products in Li-S batteries
Yu B.-C.; Jung J.-W.; Park K.; Goodenough J.B.
发表日期2017
ISSN17545692
起始页码86
结束页码90
卷号10期号:1
英文摘要Vulcanized rubber products contain polymer backbones crosslinked with sulfur to improve mechanical strength. Burning of waste rubber products emits toxic gases, and recycling of rubber by breaking the C-S bond with costly reagents and heat is also haunted by environmental concerns. The crosslinked polymers can be extracted chemically at room temperature and, by a simple solution-drop method, used to prepare a bifunctional cathode layer on the cathode current collector of a Li-S battery. The C-S bond of the crosslinking sulfur can be broken reversibly in a discharge/recharge cycle to provide a sulfur source, and the broken carbon bond can capture a lithium polysulfide soluble in a liquid organic electrolyte by forming a C-Li-S bond during discharge. During charge, the Li is extracted and the C-S bond is reformed. However, added sulfur powder is also needed in the cathode of a Li-S battery. The data also provide a low-cost way to recycle waste rubber electrochemically. © The Royal Society of Chemistry 2017.
英文关键词Cathodes; Chemical bonds; Electrolytes; Electronic Waste; Incineration; Lithium compounds; Recycling; Rubber; Rubber products; Cathode current collectors; Cross-linked polymers; Environmental concerns; Organic electrolyte; Polymer backbones; Recycling wastes; Sulfur powders; Vulcanized rubber; Lithium sulfur batteries; electrochemical method; electrode; electrolyte; lithium; polymer; power generation; recycling; rubber; sulfur
语种英语
来源期刊Energy & Environmental Science
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/190576
作者单位Texas Materials Institute, University of Texas, Austin, TX 78712, United States
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Yu B.-C.,Jung J.-W.,Park K.,et al. A new approach for recycling waste rubber products in Li-S batteries[J],2017,10(1).
APA Yu B.-C.,Jung J.-W.,Park K.,&Goodenough J.B..(2017).A new approach for recycling waste rubber products in Li-S batteries.Energy & Environmental Science,10(1).
MLA Yu B.-C.,et al."A new approach for recycling waste rubber products in Li-S batteries".Energy & Environmental Science 10.1(2017).
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