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DOI | 10.1039/c6ee02770a |
A new approach for recycling waste rubber products in Li-S batteries | |
Yu B.-C.; Jung J.-W.; Park K.; Goodenough J.B. | |
发表日期 | 2017 |
ISSN | 17545692 |
起始页码 | 86 |
结束页码 | 90 |
卷号 | 10期号:1 |
英文摘要 | Vulcanized rubber products contain polymer backbones crosslinked with sulfur to improve mechanical strength. Burning of waste rubber products emits toxic gases, and recycling of rubber by breaking the C-S bond with costly reagents and heat is also haunted by environmental concerns. The crosslinked polymers can be extracted chemically at room temperature and, by a simple solution-drop method, used to prepare a bifunctional cathode layer on the cathode current collector of a Li-S battery. The C-S bond of the crosslinking sulfur can be broken reversibly in a discharge/recharge cycle to provide a sulfur source, and the broken carbon bond can capture a lithium polysulfide soluble in a liquid organic electrolyte by forming a C-Li-S bond during discharge. During charge, the Li is extracted and the C-S bond is reformed. However, added sulfur powder is also needed in the cathode of a Li-S battery. The data also provide a low-cost way to recycle waste rubber electrochemically. © The Royal Society of Chemistry 2017. |
英文关键词 | Cathodes; Chemical bonds; Electrolytes; Electronic Waste; Incineration; Lithium compounds; Recycling; Rubber; Rubber products; Cathode current collectors; Cross-linked polymers; Environmental concerns; Organic electrolyte; Polymer backbones; Recycling wastes; Sulfur powders; Vulcanized rubber; Lithium sulfur batteries; electrochemical method; electrode; electrolyte; lithium; polymer; power generation; recycling; rubber; sulfur |
语种 | 英语 |
来源期刊 | Energy & Environmental Science |
文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/190576 |
作者单位 | Texas Materials Institute, University of Texas, Austin, TX 78712, United States |
推荐引用方式 GB/T 7714 | Yu B.-C.,Jung J.-W.,Park K.,et al. A new approach for recycling waste rubber products in Li-S batteries[J],2017,10(1). |
APA | Yu B.-C.,Jung J.-W.,Park K.,&Goodenough J.B..(2017).A new approach for recycling waste rubber products in Li-S batteries.Energy & Environmental Science,10(1). |
MLA | Yu B.-C.,et al."A new approach for recycling waste rubber products in Li-S batteries".Energy & Environmental Science 10.1(2017). |
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