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DOI10.1039/c8ee03112f
Farming thermoelectric paper
Abol-Fotouh D.; Dörling B.; Zapata-Arteaga O.; Rodríguez-Martínez X.; Gómez A.; Reparaz J.S.; Laromaine A.; Roig A.; Campoy-Quiles M.
发表日期2019
ISSN17545692
起始页码716
结束页码726
卷号12期号:2
英文摘要Waste heat to electricity conversion using thermoelectric generators is emerging as a key technology in the forthcoming energy scenario. Carbon-based composites could unleash the as yet untapped potential of thermoelectricity by combining the low cost, easy processability, and low thermal conductivity of biopolymers with the mechanical strength and good electrical properties of carbon nanotubes (CNTs). Here we use bacteria in environmentally friendly aqueous media to grow large area bacterial nanocellulose (BC) films with an embedded highly dispersed CNT network. The thick films (≈10 μm) exhibit tuneable transparency and colour, as well as low thermal and high electrical conductivity. Moreover, they are fully bendable, can conformally wrap around heat sources and are stable above 500 K, which expands the range of potential uses compared to typical conducting polymers and composites. The high porosity of the material facilitates effective n-type doping, enabling the fabrication of a thermoelectric module from farmed thermoelectric paper. Because of vertical phase separation of the CNTs in the BC composite, the grown films at the same time serve as both the active layer and separating layer, insulating each thermoelectric leg from the adjacent ones. Last but not least, the BC can be enzymatically decomposed, completely reclaiming the embedded CNTs. © 2019 The Royal Society of Chemistry.
英文关键词Biopolymers; Carbon nanotubes; Composite films; Conducting polymers; Nanocellulose; Phase separation; Semiconductor doping; Thermal conductivity; Thermoelectric equipment; Thermoelectricity; Thick films; Waste heat; Yarn; Carbon based composites; Energy scenarios; High electrical conductivity; Key technologies; Low thermal conductivity; Thermo-electric modules; Thermoelectric generators; Vertical phase separations; Boron carbide; cellulose; composite; electrical conductivity; electrical property; electricity; equipment; polymer; separation; thermal conductivity; transparency; Bacteria (microorganisms)
语种英语
来源期刊Energy & Environmental Science
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/190001
作者单位Institute of Materials Science of Barcelona (ICMAB-CSIC), Campus of the UAB, Bellaterra, 08193, Spain; City of Scientific Research and Technological Applications (SRTA-City), New Borg Al-Arab, 21934, Egypt
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GB/T 7714
Abol-Fotouh D.,Dörling B.,Zapata-Arteaga O.,et al. Farming thermoelectric paper[J],2019,12(2).
APA Abol-Fotouh D..,Dörling B..,Zapata-Arteaga O..,Rodríguez-Martínez X..,Gómez A..,...&Campoy-Quiles M..(2019).Farming thermoelectric paper.Energy & Environmental Science,12(2).
MLA Abol-Fotouh D.,et al."Farming thermoelectric paper".Energy & Environmental Science 12.2(2019).
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