气候变化领域集成服务门户(CCPortal): Unveiling dual-linkage 3D hexaiminobenzene metal-organic frameworks towards long-lasting advanced reversible Zn-air batteries

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DOI	10.1039/c8ee02679c
	Unveiling dual-linkage 3D hexaiminobenzene metal-organic frameworks towards long-lasting advanced reversible Zn-air batteries
	Shinde S.S.; Lee C.H.; Jung J.-Y.; Wagh N.K.; Kim S.-H.; Kim D.-H.; Lin C.; Lee S.U.; Lee J.-H.
发表日期	2019
ISSN	17545692
起始页码	727
结束页码	738
卷号	12 期号:2
英文摘要	Advanced Zn-air batteries (ZABs) with ultrahigh cycle life, which also harness energy with bifunctional electrochemical reactions, are significantly challenging for the commercialization of hybrid/electric vehicles and wearable electronics. Herein, we demonstrated robust aqueous and flexible ZABs with novel three-dimensional dual-linked hexaiminobenzene metal-organic framework (Mn/Fe-HIB-MOF)-based bifunctional oxygen electrocatalysts and superionic functionalized bio-cellulose electrolytes (64 mS cm -1 ). The well-defined quintet-shelled hollow sphere MOFs possess a hierarchical porous structure, excellent packing density with a surface area of 2298 m 2 g -1 , and chemical stability as compared to conventional MOFs. Mn/Fe-HIB-MOF exhibited superior bifunctional oxygen electrocatalytic activity (0.627 V) with half-wave potential (0.883 V) for oxygen reduction and overpotential (280 mV@10 mA cm -2 ) for oxygen evolution reactions, outperforming commercial Pt/C and RuO 2 . Their favorable oxygen reactions and surface electronic structures were confirmed by density functional theory. Significantly, the Mn/Fe-HIB-MOF cathode demonstrated the highest lifetimes reported to date for rechargeable ZABs, namely 1000 h (0.75 V voltage gap@10 mA cm -2 ) over 6000 cycles and 600 h (efficiency ∼65.24%@25 mA cm -2 ) over 3600 cycles with excellent flexibility for liquid and all-solid-state flexible ZABs, respectively. These promising results illustrate the great potential of these novel hexaiminobenzene MOFs and superionic bio-cellulose membranes for the commercial implementation of rechargeable ZABs. © 2019 The Royal Society of Chemistry.
英文关键词	Cellulose; Chemical stability; Crystalline materials; Electrocatalysts; Electrolytic reduction; Electronic structure; Organometallics; Oxygen; Ruthenium compounds; Surface reactions; Zinc air batteries; Commercial implementation; Electrocatalytic activity; Electrochemical reactions; Hierarchical porous structures; Hybrid/electric vehicles; Metal organic framework; Oxygen evolution reaction; Surface electronic structures; Density functional theory; catalysis; catalyst; cellulose; chemical reaction; electrochemical method; electrode; electrolyte; equipment; membrane; surface area; three-dimensional modeling; zinc; Air; Area; Bulk Density; Cellulose; Cycles; Metals; Oxygen; Ruthenium Compounds
语种	英语
来源期刊	Energy & Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/189997
作者单位	Department of Materials Science and Chemical Engineering, Hanyang University, Ansan Kyunggido, 15588, South Korea; Department of Bionano Technology, Hanyang University, Ansan Kyunggido, 15588, South Korea; Department of Chemical and Molecular Engineering, Hanyang University, Ansan Kyunggido, 15588, South Korea
推荐引用方式 GB/T 7714	Shinde S.S.,Lee C.H.,Jung J.-Y.,et al. Unveiling dual-linkage 3D hexaiminobenzene metal-organic frameworks towards long-lasting advanced reversible Zn-air batteries[J],2019,12(2).
APA	Shinde S.S..,Lee C.H..,Jung J.-Y..,Wagh N.K..,Kim S.-H..,...&Lee J.-H..(2019).Unveiling dual-linkage 3D hexaiminobenzene metal-organic frameworks towards long-lasting advanced reversible Zn-air batteries.Energy & Environmental Science,12(2).
MLA	Shinde S.S.,et al."Unveiling dual-linkage 3D hexaiminobenzene metal-organic frameworks towards long-lasting advanced reversible Zn-air batteries".Energy & Environmental Science 12.2(2019).